Reactions in single-molecule junctions
Developing new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …
catalysis, nanotechnology and materials science. Transforming one compound or material …
Boron-based stimuli responsive materials
SK Mellerup, S Wang - Chemical Society Reviews, 2019 - pubs.rsc.org
Boron-based stimuli responsive systems represent an emerging class of useful materials
with a wide variety of applications. Functions within these boron-doped molecules are …
with a wide variety of applications. Functions within these boron-doped molecules are …
Structure and reactivity/selectivity control by oriented-external electric fields
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …
Electrostatic catalysis of a Diels–Alder reaction
It is often thought that the ability to control reaction rates with an applied electrical potential
gradient is unique to redox systems. However, recent theoretical studies suggest that …
gradient is unique to redox systems. However, recent theoretical studies suggest that …
Electric fields in catalysis: From enzymes to molecular catalysts
Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …
net charges of transition states, products, and reactants to modify the free energy landscape …
Oriented electric fields as future smart reagents in chemistry
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …
Molecular approach to engineer two-dimensional devices for CMOS and beyond-CMOS applications
Two-dimensional materials (2DMs) have attracted tremendous research interest over the
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …
Selectivity in single-molecule reactions by tip-induced redox chemistry
Controlling selectivity of reactions is an ongoing quest in chemistry. In this work, we
demonstrate reversible and selective bond formation and dissociation promoted by tip …
demonstrate reversible and selective bond formation and dissociation promoted by tip …
Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box
Static electricity is central to many day-to-day practical technologies, from separation
methods in the recycling of plastics to transfer inks in photocopying, but the exploration of …
methods in the recycling of plastics to transfer inks in photocopying, but the exploration of …
Elucidating the roles of electric fields in catalysis: a perspective
This Perspective illustrates how the presence of internal and external electric fields can
affect catalytic activity and selectivity, with a focus on heterogeneous catalysts. Specifically …
affect catalytic activity and selectivity, with a focus on heterogeneous catalysts. Specifically …