Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Developing new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

Boron-based stimuli responsive materials

SK Mellerup, S Wang - Chemical Society Reviews, 2019 - pubs.rsc.org
Boron-based stimuli responsive systems represent an emerging class of useful materials
with a wide variety of applications. Functions within these boron-doped molecules are …

Structure and reactivity/selectivity control by oriented-external electric fields

S Shaik, R Ramanan, D Danovich… - Chemical Society …, 2018 - pubs.rsc.org
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …

Electrostatic catalysis of a Diels–Alder reaction

AC Aragones, NL Haworth, N Darwish, S Ciampi… - Nature, 2016 - nature.com
It is often thought that the ability to control reaction rates with an applied electrical potential
gradient is unique to redox systems. However, recent theoretical studies suggest that …

Electric fields in catalysis: From enzymes to molecular catalysts

NG Léonard, R Dhaoui, T Chantarojsiri, JY Yang - ACS catalysis, 2021 - ACS Publications
Electric fields underlie all reactions and impact reactivity by interacting with the dipoles and
net charges of transition states, products, and reactants to modify the free energy landscape …

Oriented electric fields as future smart reagents in chemistry

S Shaik, D Mandal, R Ramanan - Nature chemistry, 2016 - nature.com
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …

Molecular approach to engineer two-dimensional devices for CMOS and beyond-CMOS applications

Y Zhao, M Gobbi, LE Hueso, P Samorì - Chemical Reviews, 2021 - ACS Publications
Two-dimensional materials (2DMs) have attracted tremendous research interest over the
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …

Selectivity in single-molecule reactions by tip-induced redox chemistry

F Albrecht, S Fatayer, I Pozo, I Tavernelli, J Repp… - Science, 2022 - science.org
Controlling selectivity of reactions is an ongoing quest in chemistry. In this work, we
demonstrate reversible and selective bond formation and dissociation promoted by tip …

Harnessing electrostatic catalysis in single molecule, electrochemical and chemical systems: a rapidly growing experimental tool box

S Ciampi, N Darwish, HM Aitken, I Díez-Pérez… - Chemical Society …, 2018 - pubs.rsc.org
Static electricity is central to many day-to-day practical technologies, from separation
methods in the recycling of plastics to transfer inks in photocopying, but the exploration of …

Elucidating the roles of electric fields in catalysis: a perspective

F Che, JT Gray, S Ha, N Kruse, SL Scott… - ACS …, 2018 - ACS Publications
This Perspective illustrates how the presence of internal and external electric fields can
affect catalytic activity and selectivity, with a focus on heterogeneous catalysts. Specifically …