Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters

H Shen, G Tian, Z Xu, L Wang, Q Wu, Y Zhang… - Coordination Chemistry …, 2022 - Elsevier
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …

Chemically modified gold/silver superatoms as artificial elements at nanoscale: design principles and synthesis challenges

S Takano, T Tsukuda - Journal of the American Chemical Society, 2021 - ACS Publications
Pure and doped gold/silver clusters protected by monolayers of organic ligands have
attracted much interest as novel functional materials owing to their nonbulk-like, size-specific …

N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters

EL Albright, TI Levchenko, VK Kulkarni… - Journal of the …, 2024 - ACS Publications
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …

Seeing ligands on nanoclusters and in their assemblies by X-ray crystallography: atomically precise nanochemistry and beyond

Y Li, R Jin - Journal of the American Chemical Society, 2020 - ACS Publications
Ligands are of tremendous importance for colloidal nanoparticles (NPs) in terms of surface
protection, size and shape control, tailoring properties, self-assembly, and applications …

Preorganized Nitrogen Sites for Au11 Amidation: A Generalizable Strategy toward Precision Functionalization of Metal Nanoclusters

Y Zhang, SR He, Y Yang, TS Zhang… - Journal of the …, 2023 - ACS Publications
Atomically precise metal nanoclusters have received tremendous attention due to their
unique structures and properties. Although synthetic approaches to this kind of nanomaterial …

Superatomic Au13 clusters ligated by different N-heterocyclic carbenes and their ligand-dependent catalysis, photoluminescence, and proton sensitivity

H Shen, S Xiang, Z Xu, C Liu, X Li, C Sun, S Lin… - Nano Research, 2020 - Springer
We report herein a class of superatomic Au 13 clusters stabilized by different N-heterocyclic
carbenes (NHCs). The clusters show diverse metal surface structures, properties and …

Toward controlling the electronic structures of chemically modified superatoms of gold and silver

T Omoda, S Takano, T Tsukuda - Small, 2021 - Wiley Online Library
Atomically precise gold/silver clusters protected by organic ligands L,[(Au/Ag) xLy] z, have
gained increasing interest as building units of functional materials because of their novel …

Progress, enhancement mechanisms and applications of electrochemiluminescence and photoluminescence metal nanoclusters

W Guo, L Zhao, L Jiang, Y Nie, Y Zhou - TrAC Trends in Analytical …, 2024 - Elsevier
In recent years, luminescent metal nanoclusters (metal NCs) with the unique features of
intriguing optical properties and excellent biocompatibility, have emerged as a promising …

An organic–inorganic hybrid material based on benzo [ghi] perylenetri-imide and cyclic titanium-oxo cluster for efficient perovskite and organic solar cells

Z Zhang, F Han, J Fang, C Zhao, S Li, Y Wu… - CCS …, 2022 - chinesechemsoc.org
Perovskite and organic solar cells usually require electron-transport interlayers to efficiently
transport electrons from the photoactive layer to the metal electrode. In general, pure organic …