Bond-forming and-breaking reactions at sulfur (IV): sulfoxides, sulfonium salts, sulfur ylides, and sulfinate salts
D Kaiser, I Klose, R Oost, J Neuhaus… - Chemical …, 2019 - ACS Publications
Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …
development of novel chemical structures and architectures. Prominent among these …
Recent advances of 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) in photocatalytic transformations
TY Shang, LH Lu, Z Cao, Y Liu, WM He… - Chemical …, 2019 - pubs.rsc.org
1, 2, 3, 5-Tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) is a typical donor–acceptor
fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron …
fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron …
Evolution and Future of Hetero‐and Hydro‐Trifluoromethylations of Unsaturated C− C Bonds
S Kawamura, P Barrio, S Fustero… - Advanced Synthesis …, 2023 - Wiley Online Library
The difunctionalizative trifluoromethylation of unsaturated C− C bonds is a highly useful and
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …
efficient method for the synthesis of trifluoromethyl compounds with attractive architectures …
Electrochemical Installation of CFH2−, CF2H−, CF3−, and Perfluoroalkyl Groups into Small Organic Molecules
CM Kisukuri, VA Fernandes, JAC Delgado… - The Chemical …, 2021 - Wiley Online Library
Electrosynthesis can be considered a powerful and sustainable methodology for the
synthesis of small organic molecules. Due to its intrinsic ability to generate highly reactive …
synthesis of small organic molecules. Due to its intrinsic ability to generate highly reactive …
Direct C (sp 3)–H difluoromethylation via radical–radical cross-coupling by visible-light photoredox catalysis
W Xiong, WB Qin, YS Zhao, KZ Fu… - Organic Chemistry …, 2022 - pubs.rsc.org
Herein, a radical–radical cross-coupling strategy for direct difluoromethylation of the C (sp3)–
H bond is reported. This transformation was readily accomplished under transition metal …
H bond is reported. This transformation was readily accomplished under transition metal …
Visible-Light-Initiated Sequential Trifluoromethylation/Remote C(sp3)–H Alkynylation of Vinyl Azides by Radical Relay
Z Chen, Y Duan, S Sun, B Lin, X Liu… - The Journal of Organic …, 2023 - ACS Publications
A visible-light-initiated trifluoromethylation/remote aliphatic C–H alkynylation of α-alkyl-
substituted vinyl azides using acetylenic triflones as both the trifluoromethyl and alkyne …
substituted vinyl azides using acetylenic triflones as both the trifluoromethyl and alkyne …
Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of α-CF2H-Substituted Ketones in Flow
A step-economical method for synthesis of α-CF2H-substituted ketones from readily
available alkene feedstocks has been developed. Radical difluoromethylation of aromatic …
available alkene feedstocks has been developed. Radical difluoromethylation of aromatic …
Benzodithiazoles‐Sulfoximines: Preparation, Properties and Reactivities as Radical Perfluoroalkylating Agents
T Duhail, S Messaoudi, G Dagousset… - Advanced Synthesis …, 2023 - Wiley Online Library
We describe the preparation of S‐perfluoroalkyl benzodithiazole trioxides as radical
perfluoroalkylating reagents. Their syntheses were performed on a multi‐gram scale by an …
perfluoroalkylating reagents. Their syntheses were performed on a multi‐gram scale by an …
Renewable electricity enables green routes to fine chemicals and pharmaceuticals
A Murtaza, MA Qamar, K Saleem… - The Chemical …, 2022 - Wiley Online Library
Syntheses of chemicals using renewable electricity and when generating high atom
economies are considered green and sustainable processes. In the present state of affairs …
economies are considered green and sustainable processes. In the present state of affairs …
Electrochemical trifluoromethylation/semipinacol rearrangement sequences of alkenyl alcohols: synthesis of β-CF 3-substituted ketones
H Im Jung, Y Kim, DY Kim - Organic & Biomolecular Chemistry, 2019 - pubs.rsc.org
Electrochemical oxidative radical trifluoromethylation/semipinacol rearrangement
sequences of alkenyl alcohols were developed in this study. This approach is …
sequences of alkenyl alcohols were developed in this study. This approach is …