Recent advances in nanozymes: from matters to bioapplications

Y Ai, ZN Hu, X Liang, H Sun, H Xin… - Advanced Functional …, 2022 - Wiley Online Library
The manufacture of bionic materials to simulate the natural counterparts has attracted
extensive attention. As one of the subcategories of biomimetic materials, the development of …

Reactivity of metal–oxo clusters towards biomolecules: from discrete polyoxometalates to metal–organic frameworks

DES Marcano, ND Savić, K Declerck… - Chemical Society …, 2024 - pubs.rsc.org
Metal–oxo clusters hold great potential in several fields such as catalysis, materials science,
energy storage, medicine, and biotechnology. These nanoclusters of transition metals with …

Nanozyme-enabled analytical chemistry

S Li, Y Zhang, Q Wang, A Lin, H Wei - Analytical Chemistry, 2021 - ACS Publications
In 2007, landmark research recognized ferromagnetic nanoparticles (Fe3O4 NPs) as the
substitute of horseradish peroxidase (HRP) for their alike catalytic ability to oxidize signal …

Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals

D Van den Eynden, R Pokratath, J De Roo - Chemical Reviews, 2022 - ACS Publications
We review the nonaqueous precursor chemistry of the group 4 metals to gain insight into the
formation of their oxo clusters and colloidal oxide nanocrystals. We first describe the …

Au3+‐Functionalized UiO‐67 Metal‐Organic Framework Nanoparticles: O2•− and •OH Generating Nanozymes and Their Antibacterial Functions

MM Pan, Y Ouyang, YL Song, LQ Si, M Jiang, X Yu… - Small, 2022 - Wiley Online Library
The synthesis and characterization of Au3+‐modified UiO‐67 metal‐organic framework
nanoparticles, Au3+‐NMOFs, are described. The Au3+‐NMOFs reveal dual oxidase‐like …

The forgotten chemistry of group (IV) metals: A survey on the synthesis, structure, and properties of discrete Zr (IV), Hf (IV), and Ti (IV) oxo clusters

Y Zhang, F de Azambuja, TN Parac-Vogt - Coordination Chemistry Reviews, 2021 - Elsevier
Group (IV) metal oxo clusters are a diverse class of compounds with rapidly growing
applications in catalysis, materials chemistry, electronics and optics. They possess unique …

Metal–organic framework-engineered enzyme/nanozyme composites: Preparation, functionality, and sensing mechanisms

Y Li, H Chai, Z Yuan, C Huang, S Wang, Y Sun… - Chemical Engineering …, 2024 - Elsevier
The utility of non-homogeneous nanomaterials for the immobilization of enzymes has been
demonstrated to enhance their catalytic performance. Alongside this, the advent of artificial …

The dawn of metal-oxo clusters as artificial proteases: from discovery to the present and beyond

F Azambuja, J Moons… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus The selective cleavage of peptide bonds in proteins is of paramount importance
in many areas of the biological and medical sciences, playing a key role in protein …

En route to a heterogeneous catalytic direct peptide bond formation by Zr-based metal–organic framework catalysts

F de Azambuja, A Loosen, D Conic… - Acs …, 2021 - ACS Publications
Peptide bond formation is a challenging, environmentally and economically demanding
transformation. Catalysis is key to circumvent current bottlenecks. To date, many …

A zirconium metal-organic framework with SOC topological net for catalytic peptide bond hydrolysis

S Wang, HGT Ly, M Wahiduzzaman, C Simms… - Nature …, 2022 - nature.com
The discovery of nanozymes for selective fragmentation of proteins would boost the
emerging areas of modern proteomics, however, the development of efficient and reusable …