Probing the Kinetic Origin of Varying Oxidative Stability of Ethyl‐vs. Propyl‐spaced Amines for Direct Air Capture

S Li, MR Cerón, HV Eshelman, AJ Varni… - …, 2023 - Wiley Online Library
Amine‐based adsorbents are promising for direct air capture of CO2, yet oxidative
degradation remains a key unmitigated risk hindering wide‐scale deployment. Borrowing …

Evaluation of molecular photophysical and photochemical properties using linear response time-dependent density functional theory with classical embedding …

WZ Liang, Z Pei, Y Mao, Y Shao - The Journal of Chemical Physics, 2022 - pubs.aip.org
Time-dependent density functional theory (TDDFT) based approaches have been
developed in recent years to model the excited-state properties and transition processes of …

Describing Polytopal Rearrangements of Fluxional Molecules with Curvilinear Coordinates Derived from Normal Vibrational Modes: A Conceptual Extension of …

W Zou, Y Tao, E Kraka - Journal of Chemical Theory and …, 2020 - ACS Publications
In this work a new curvilinear coordinate system is presented for the comprehensive
description of polytopal rearrangements of N-coordinate compounds (N= 4–7) and systems …