The array of transition-metal-catalyzed cross-coupling reactions can easily be considered
nowadays cornerstones in the field of organic synthesis. 1, 2 Among them, the palladium …

The biheteroaryl structural motif is prevalent in polymers, advanced materials, liquid crystals,
ligands, molecules of medicinal interest, and natural products. Many types of synthetic …

Easy does it: The unique properties of benziodoxolone alkynyl periodinane 1 and gold
catalysts have allowed the development of a high yielding, operationally simple (room …

Among the known aromatic nitrogen heterocycles, pyrrole represents a privileged aromatic
heterocycle ranging its occurrence in the key component of “pigments of life” to biologically …

Conspectus Cross-coupling reactions, especially those that are catalyzed by palladium,
have revolutionized the way in which carbon–carbon bonds can be formed. The most …

Lamellarins are natural products isolated from marine invertebrates having a unique
heterocyclic ring system. Many of these natural products exhibit potentially useful biological …

We have disclosed a new synthetic method for the rapid assembly of poly-substituted
pyrroles with readily accessible oximes and azadienes as the starting materials. The present …

A convergent total synthesis of lamellarins S and Z is described. The synthesis features a
halogen dance of an easily accessible α, β-dibromopyrrole promoted by an ester moiety …

Despite the tremendous utilities of metal‐mediated cross‐couplings in modern organic
chemistry, coupling reactions involving nitrogenous heteroarenes remain a challenging …

Arylsulfinyl groups direct the metal-free, regiospecific, nucleophilic ortho-allylation of
pyrroles and pyrazoles. Mechanistic studies support the intermediacy of allylsulfonium salts …