Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Recent advances in the synthesis of nitrogen heterocycles using arenediazonium salts as nitrogen sources

J Liu, J Jiang, L Zheng, ZQ Liu - Advanced Synthesis & …, 2020 - Wiley Online Library
Nitrogen heterocycles are important structural subunits that occur widely in bioactive natural
products, pharmaceuticals, agrochemicals, dyes, cosmetics, and functional materials …

Domino CH sulfonylation and pyrazole annulation for fully substituted pyrazole synthesis in water using hydrophilic enaminones

Y Guo, G Wang, L Wei, JP Wan - The Journal of Organic …, 2019 - ACS Publications
The cascade reactions between NH 2-functionalized enaminones and sulfonyl hydrazines
have been developed for the synthesis of fully substituted pyrazoles. By making use of the …

Aryl Diazonium Salt‐Triggered Cyclization and Cycloaddition Reactions: Past, Present, and Future

FG Zhang, Z Chen, CW Cheung… - Chinese Journal of …, 2020 - Wiley Online Library
Aryl diazonium salts occupy a privileged role in synthetic chemistry owing to their ready
availability and versatile reactivity. While their applications in accessing diversely …

Copper-mediated tandem ring-opening/cyclization reactions of cyclopropanols with aryldiazonium salts: synthesis of N-arylpyrazoles

J Liu, E Xu, J Jiang, Z Huang, L Zheng… - Chemical …, 2020 - pubs.rsc.org
A general method for the synthesis of structurally diverse N-arylpyrazoles from readily
available cyclopropanols and aryldiazonium salts is disclosed. The reaction was conducted …

Copper-promoted aerobic oxidative [3+ 2] cycloaddition reactions of N, N-disubstituted hydrazines with alkynoates: access to substituted pyrazoles

X Zou, L Zheng, X Zhuo, Y Zhong, Y Wu… - The Journal of …, 2023 - ACS Publications
A copper-promoted aerobic oxidative [3+ 2] cycloaddition reaction for the synthesis of
various substituted pyrazoles from N, N-disubstituted hydrazines with alkynoates in the …

Aryldiazonium salts serve as a dual synthon: construction of fully substituted pyrazoles via rongalite-mediated three-component radical annulation reaction

M Wang, BC Tang, JC Xiang, XL Chen, JT Ma… - Organic …, 2019 - ACS Publications
A highly efficient rongalite-mediated three-component radical annulation reaction to furnish
fully substituted pyrazoles from aryldiazonium salts and α, β-unsaturated aldehydes or …

[HTML][HTML] Recent Developments in the Synthesis of β-Diketones

G de Gonzalo, AR Alcántara - Pharmaceuticals, 2021 - mdpi.com
Apart from being one of the most important intermediates in chemical synthesis, broadly
used in the formation of C–C bonds among other processes, the β-dicarbonyl structure is …

Transition Metal-Free De Novo Synthesis of Sulfonated Pyrazoles from Sulfonyl Hydrazides, 1, 3-Diketones, and Sodium Sulfinates at Room Temperature

J Chen, D Chen, J Kuang, Y Ma - The Journal of Organic …, 2021 - ACS Publications
A transition metal-free method for de novo construction of diverse sulfonated pyrazoles from
readily available sulfonyl hydrazides, 1, 3-diketones, and sodium sulfinates was established …

Aryl pyrazoles from photocatalytic cycloadditions of arenediazonium

L Cardinale, M Neumeier, M Majek… - Organic …, 2020 - ACS Publications
A photocatalytic synthesis of 1, 5-diaryl pyrazoles from arenediazoniums and
arylcyclopropanols is reported. The reaction proceeded under mild conditions (rt, 20 min) …