Tetryliumylidene ions in synthesis and catalysis
S Stigler, S Fujimori, A Kostenko, S Inoue - Chemical Science, 2024 - pubs.rsc.org
Tetryliumylidene ions ([R–E:]+), recognised for their intriguing electronic properties, have
attracted considerable interest. These positively charged species, with two vacant p-orbitals …
attracted considerable interest. These positively charged species, with two vacant p-orbitals …
Low Valent N‐Coordinated Cations and Dications of Heavier Group 14 Elements: Lewis Acids or Bases?
R Jambor, M Novák - European Journal of Inorganic Chemistry, 2023 - Wiley Online Library
Low‐valent N‐coordinated cations and dications of heavier group 14 elements are of great
interest in recent years. Their unique electronic structure gives them an ambiphilic character …
interest in recent years. Their unique electronic structure gives them an ambiphilic character …
Isolation and Reactivity of Chlorotetryliumylidenes Using a Bidentate Bis (N-heterocyclic imine) Ligand
FS Tschernuth, F Hanusch, T Szilvási, S Inoue - Organometallics, 2020 - ACS Publications
By use of the ethylene-bridged bidentate bis-NHI (NHI= N-heterocyclic imine) ligand 1
toward the complexation of ECl2·(dioxane)(E= Ge, Sn) the synthesis of the first bis-NHI …
toward the complexation of ECl2·(dioxane)(E= Ge, Sn) the synthesis of the first bis-NHI …
Chemistry of the Bis (imine)‐Based Tetradentate Ligand Stabilized Group 14 E (II) Cations (E= Ge and Sn)
S Biswas, N Patel, R Deb, M Majumdar - The Chemical Record, 2022 - Wiley Online Library
The ambiphilic Ge (II) and Sn (II) cationic species have been reported to be isolated through
kinetic or thermodynamic stabilizations. Nonetheless, steric congestion or excessive …
kinetic or thermodynamic stabilizations. Nonetheless, steric congestion or excessive …
A Non-innocent Ligand Supported Germylene and Its Diverse Reactions
KH Chen, YH Liu, CW Chiu - Organometallics, 2020 - ACS Publications
To expand the reactivity scope of divalent germanium, an α-iminopyridine supported
dicoordinate germanium complex (2) was prepared from deamination of the corresponding …
dicoordinate germanium complex (2) was prepared from deamination of the corresponding …
The reactivity of N-heterocyclic germylenes and stannylenes based on 9, 10-phenanthrendiimines towards metal carbonyls and sulfur
GG Kazakov, NO Druzhkov, EV Baranov… - Journal of …, 2021 - Elsevier
The reactivity of germylene and stannylene based on 9, 10-phenanthrenediimine are
described. Complexes of nickel and iron carbonyls with a coordinated germylene were …
described. Complexes of nickel and iron carbonyls with a coordinated germylene were …
Recent Advances in the Chemistry of Germanium (II) Cationic Compounds
The syntheses and stabilizations of germanium (II) cationic compounds have been known
for long. Contemporary research have been engaged in tailoring the germanium (II) cationic …
for long. Contemporary research have been engaged in tailoring the germanium (II) cationic …