Aza-Michael reaction: achievements and prospects

AY Rulev - Russian Chemical Reviews, 2011 - iopscience.iop.org
Data published in the last 10 years on the use of the aza-Michael reaction in organic
synthesis are described systematically. The attention is focused on environmentally friendly …

The aza-Michael reaction as an alternative strategy to generate advanced silicon-based (macro) molecules and materials

A Genest, D Portinha, E Fleury, F Ganachaud - Progress in Polymer …, 2017 - Elsevier
Aza-Michael reaction is a simple and accessible addition reaction performed at moderate
temperature, possibly without a catalyst and without releasing by-products. Its versatility …

1, 8-Diazabicyclo [5.4. 0] undec-7-ene (DBU)-promoted efficient and versatile aza-Michael addition

CE Yeom, MJ Kim, BM Kim - Tetrahedron, 2007 - Elsevier
A convenient and versatile method was developed for aza-Michael addition using a
substoichiometric amount of 1, 8-diazabicyclo [5.4. 0] undec-7-ene (DBU). Various nitrogen …

Boric acid: a novel and safe catalyst for aza-Michael reactions in water

MK Chaudhuri, S Hussain, ML Kantam, B Neelima - Tetrahedron Letters, 2005 - Elsevier
Boric acid: a novel and safe catalyst for aza-Michael reactions in water - ScienceDirect Skip to
main contentSkip to article Elsevier logo Journals & Books Search RegisterSign in View PDF …

Glycerol as an efficient promoting medium for organic reactions

Y Gu, J Barrault, F Jerome - Advanced synthesis & catalysis, 2008 - Wiley Online Library
Whereas the beneficial effect of water on reaction rate is decreased with an increase of the
reactant′ s hydrophobicity, we report here that the use of glycerol as solvent was able to …

Deciphering the Microdroplet Acceleration Factors of Aza-Michael Addition Reactions

Z Song, C Zhu, K Gong, R Wang, J Zhang… - Journal of the …, 2024 - ACS Publications
Microdroplet chemistry is emerging as a great tool for accelerating reactions by several
orders of magnitude. Several unique properties such as extreme pHs, interfacial electric …

β-Cyclodextrin promoted aza-Michael addition of amines to conjugated alkenes in water

K Surendra, NS Krishnaveni, R Sridhar, KR Rao - Tetrahedron letters, 2006 - Elsevier
Highly efficient and environmentally benign aza-Michael additions of amines to α, β-
unsaturated compounds catalyzed by β-cyclodextrin in water to produce the corresponding …

Polyethylene glycol as a non-ionic liquid solvent for Michael addition reaction of amines to conjugated alkenes

R Kumar, P Chaudhary, S Nimesh, R Chandra - Green Chemistry, 2006 - pubs.rsc.org
Polyethylene glycol (PEG) is found to be an inexpensive, non-toxic, environmentally friendly
reaction medium for the conjugate addition of amines to conjugated alkenes to afford the …

Innovative catalysis in Michael addition reactions for CX bond formation

RS Malkar, AL Jadhav, GD Yadav - Molecular Catalysis, 2020 - Elsevier
The Michael addition reaction is one of the most classical reactions in organic synthesis as it
is widely applied to synthesis of CX (XC,= O, N, S) bonds to produce natural compounds …

Highly efficient aza-Michael reactions of aromatic amines and N-heterocycles catalyzed by a basic ionic liquid under solvent-free conditions

L Yang, LW Xu, W Zhou, L Li, CG Xia - Tetrahedron Letters, 2006 - Elsevier
A task-specific basic ionic liquid,[Bmim] OH, has been introduced as a catalyst for the aza-
Michael addition of aromatic amines and N-heterocycles to cyclic or acyclic ketones under …