Synthesis and functionalization of porphyrins through organometallic methodologies

S Hiroto, Y Miyake, H Shinokubo - Chemical reviews, 2017 - ACS Publications
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

Conjugated porphyrin arrays: synthesis, properties and applications for functional materials

T Tanaka, A Osuka - Chemical Society Reviews, 2015 - pubs.rsc.org
Conjugated porphyrin arrays that possess delocalised electronic networks have, for the most
part, been assembled by using alkene or alkyne type bridging units or by directly connecting …

Expanding the porphyrin π-system by fusion with anthracene

NKS Davis, M Pawlicki, HL Anderson - Organic Letters, 2008 - ACS Publications
Synthesis of β, meso, β-anthracene triply fused and β, meso-anthracene doubly fused
porphyrins has been achieved via oxidative intramolecular ring closure of meso-(9-anthryl) …

Merging porphyrins with organometallics: synthesis and applications

BMJM Suijkerbuijk… - Angewandte Chemie …, 2008 - Wiley Online Library
The coordination chemistry of porphyrins has traditionally involved the ability of the
porphyrin's tetrapyrrolic core to accommodate metal ions of varying charges and sizes, and …

The Heck reaction for porphyrin functionalisation: synthesis of meso-alkenyl monoporphyrins and palladium-catalysed formation of unprecedented meso–β ethene …

OB Locos, DP Arnold - Organic & Biomolecular Chemistry, 2006 - pubs.rsc.org
Palladium-catalysed coupling of the vinyl derivatives methyl acrylate, styrene and
acrylonitrile with 5-bromo-10, 15, 20-triphenylporphyrin (MTriPPBr; M= 2H, Ni, Zn) and 5, 15 …

Engineering conjugation in para-phenylene-bridged porphyrin tapes

M Pawlicki, M Morisue, NKS Davis, DG McLean… - Chemical …, 2012 - pubs.rsc.org
We report the synthesis of 7 new para-phenylene-bridged zinc porphyrin dimers, five of
which were characterized by single-crystal X-ray analysis. A variety of links were tested for …

Synthesis of new azido porphyrins and their reactivity in copper (I)-catalyzed Huisgen 1, 3-dipolar cycloaddition reaction with alkynes

M Séverac, L Le Pleux, A Scarpaci, E Blart, F Odobel - Tetrahedron Letters, 2007 - Elsevier
We report herein the preparation of two novel porphyrins substituted with an azido group
born either on the para-position of one phenyl meso-susbtituent of a tetraaryl zinc porphyrin …

State-Selective Electron Transfer in an Unsymmetric Acceptor−Zn(II)porphyrin−Acceptor Triad: Toward a Controlled Directionality of Electron Transfer from the Porphyrin S2 and …

S Wallin, C Monnereau, E Blart… - The Journal of …, 2010 - ACS Publications
A series of Zn (II) porphyrin (ZnP) compounds covalently linked to different electron acceptor
units, naphthaleneimide (NI) and naphthalenediimide (NDI), are reported. The aim was to …

Regioselective β-Metalation of meso-Phosphanylporphyrins. Structure and Optical Properties of Porphyrin Dimers Linked by Peripherally Fused …

Y Matano, K Matsumoto, Y Nakao, H Uno… - Journal of the …, 2008 - ACS Publications
meso-Diphenylphosphanylporphyrins were successfully prepared via Pd-catalyzed C− P
cross-coupling reaction of the corresponding meso-iodoporphyrins with …

Effects of carbon–metal–carbon linkages on the optical, photophysical, and electrochemical properties of phosphametallacycle-linked coplanar porphyrin dimers

Y Matano, K Matsumoto, H Hayashi… - Journal of the …, 2012 - ACS Publications
5-(Diphenylphosphanyl)-10, 15, 20-triarylporphyrins (meso-phosphanylporphyrins)
underwent complexations with palladium (II) and platinum (II) salts to afford …