Bermuda triangle: The first molecule containing a cyclic three‐membered Sn C P ring
has been synthesized and characterized. This SnII P Lewis pair reacts at room …

The synthesis of stable heavier analogues of nitriles as monomeric tetrylene–
phosphinidenes MesTerEP (IDipp)(E= Ge, Sn; MesTer= 2, 6-Mes2C6H3, IDipp= C ([N-(2, 6-i …

The heavier group 14 elements Ge, Sn and Pb form a wide array of complexes with anionic
P-donor ligands. This review surveys the synthesis, structures and, where pertinent …

A series of new germylene compounds has been synthesized offering systematic variation in
the σ‐and π‐capabilities of the α‐substituent and differing levels of reactivity towards E− H …

Reactions of the solution stable, two-coordinate hydrido-tetrylenes,: E (H)(L†)(E= Ge or Sn;
L†=–N (Ar†)(SiPri3); Ar†= C6H2 {C (H) Ph2} 2Pri-2, 6, 4), with a variety of unactivated cyclic …

The aryl (imino) stannylene MesTer [N (IDipp)] Sn could be obtained by treating NHILi (NHI=
N (IDipp), IDipp= C [N‐(2, 6‐iPr2C6H3) CH] 2) with MesTerSnCl (MesTer= 2, 6‐Mes2C6H3) …

An N, P‐heterocyclic germylene/B (C6F5) 3 Lewis adduct 2 presenting multi‐reactive sites
(P/B Lewis pair, germylene, Ge= P π‐bond) is reported. In contrast to classical frustrated …

Herein, the synthesis of new low‐valent Group 14 phosphinidenide complexes [({SIDipp} P)
2m] exhibiting P–M pπ–pπ interactions (SIDipp= 1, 3‐bis (2, 6‐diisopropylphenyl) …

Intramolecular stannylene-based Lewis pairs with phosphine Lewis bases were synthesized
at the ortho position in benzene or the peri position in acenaphthene. The spectroscopic …

Abstract Nitriles (R–C≡ N) have been investigated since the late eighteenth century and are
ubiquitous encounters in organic and inorganic syntheses. In contrast, heavier nitriles, which …