Recent advances in S–S bond formation

B Mandal, B Basu - RSC Advances, 2014 - pubs.rsc.org
Organic compounds possessing S–S bonds, often called disulfides or more specifically
disulfanes, have been widely applied in various fields ranging from biochemistry to different …

Sulfur–sulfur bond construction

M Wang, X Jiang - Sulfur Chemistry, 2019 - Springer
Disulfide, as a common structural motif, has been frequently used in pharmaceuticals, nature
products, and chemical biology. This chapter focuses on the methodologies that were …

Electro‐oxidative S− H/S− H cross‐coupling with hydrogen evolution: facile access to unsymmetrical disulfides

P Huang, P Wang, S Tang, Z Fu, A Lei - Angewandte Chemie, 2018 - Wiley Online Library
Sulfur is an essential element because it exists widely in proteins. The disulfide bond is an
important moiety in many different types of significant organic molecules. A new approach …

Polysulfurating reagent design for unsymmetrical polysulfide construction

X Xiao, J Xue, X Jiang - Nature communications, 2018 - nature.com
From life science to material science, to pharmaceutical industry, and to food chemistry,
polysulfides are vital structural scaffolds. However, there are limited synthetic methods for …

Recent developments in disulfide bond formation

D Witt - Synthesis, 2008 - thieme-connect.com
This review summarizes the recent developments of disulfide bond formation with a variety
of reagents. The scope and limitations of the presented methods are discussed. The …

Radical substitution provides a unique route to disulfides

Z Wu, DA Pratt - Journal of the American Chemical Society, 2020 - ACS Publications
Radical substitution on tetrasulfides is demonstrated to be a highly effective means to
prepare unsymmetric disulfides. Alkyl and aryl radicals generated thermally or …

Efficient and practical synthesis of unsymmetrical disulfides via base-catalyzed aerobic oxidative dehydrogenative coupling of thiols

X Qiu, X Yang, Y Zhang, S Song, N Jiao - Organic Chemistry Frontiers, 2019 - pubs.rsc.org
An efficient M2CO3-catalyzed (M= K or Cs) aerobic cross dehydrogenative coupling reaction
of thiols was described. This reaction provided an efficient approach to unsymmetrical …

Thiol Chlorination with N-Chlorosuccinimide: HCl-Catalyzed Release of Molecular Chlorine and the Dichotomous Effects of Water

A García-Domínguez, NM West, RT Hembre… - ACS …, 2023 - ACS Publications
The kinetics of the conversion of thiophenols into sulfenyl chlorides using N-
chlorosuccinimide (NCS) in dichloromethane have been investigated by in situ 1H NMR and …

Phthalimide-carried disulfur transfer to synthesize unsymmetrical disulfanes via copper catalysis

J Zou, J Chen, T Shi, Y Hou, F Cao, Y Wang… - ACS …, 2019 - ACS Publications
A versatile Cu-catalyzed cross-coupling reaction to various unsymmetrical disulfanes has
been presented, from phthalimide-carried disulfur transfer reagents and commercially …

Bilateral Unsymmetrical Disulfurating Reagent Design for Polysulfide Construction

Q Yu, X Zhang, X Jiang - Angewandte Chemie, 2024 - Wiley Online Library
Polysulfides are significant compounds in life science, pharmaceutical science, and
materials science. Therefore, polysulfide construction is in great demand. The controllable …