Sustainable hydrogen production through water splitting provides an appealing solution for
hydrogen energy to achieve a carbon neutral future. However, the realization and scalability …

Abstract Development of effective transition metal catalysts to replace precious metal
platinum-based electrocatalysts for hydrogen evolution reaction (HER) has attracted …

Carbon electrocatalysts consisting of metal complexes such as MNx or MSx are promising
alternatives to high‐cost Pt catalysts for the hydrogen evolution reaction (HER). However …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Multicomponent metallacages can integrate the functions of their different building blocks to
achieve synergetic effects for advanced applications. Herein, based on metal‐coordination …

Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

For the last few decades, coordination chemists have seen many ligands whose role
pervades far beyond being a supporting ancillary. The ambiguity in their electronic structure …

A central issue in the design of reactions and catalysts based on metal complexes is the
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …

Molecular design to improve catalyst performance is significant but challenging. In enzymes,
residue groups that are close to reaction centers play critical roles in regulating activities …

In this study, we report the electrocatalytic behavior of the neutral, monomeric Cu (II)
complex of diacetyl-bis (N-4-methyl-3-thiosemicarbazonato), CuL1, for metal-assisted ligand …