The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Conspectus Nickel complexes exhibit distinct properties from other group 10 metals,
including a small nuclear radius, high paring energy, low electronegativity, and low redox …

Mechanistic investigations of the Ni-catalyzed asymmetric reductive alkenylation of N-
hydroxyphthalimide (NHP) esters and benzylic chlorides are reported. Investigations of the …

For photocatalytic CO 2 reduction, directional charge-transfer channel and abundant active
sites are of significance. Herein, we designed and fabricated phosphate modified octahedral …

For photocatalytic CO2 reduction, the synergistic effect of Lewis acidity and basicity on CO2
activation is worthy of study. On the basis of a large number of oxygen defects (Lewis acidity) …

Herein, we report the direct carboxylation of unactivated secondary alkyl bromides enabled
by the merger of photoredox and nickel catalysis, a previously inaccessible endeavor in the …

The synthetic potential of carbon dioxide as an abundant and renewable C1 chemical
feedstock has attracted considerable attention in the past decade with a particular focus on …

In contrast to previous approaches to chiral α‐aryl carboxylic acids that based on reactions
using hazardous gases, pressurized setup and mostly noble metal catalysts, in this work, a …

Low-valent organonickel radical complexes are common intermediates in cross-coupling
reactions and metalloenzyme-mediated processes. The electronic structures of N-ligand …

Conspectus Despite the plethora of metal catalyzed reactions for CO2 utilization that have
been developed in academic laboratories, practical systems remain elusive. The …