The first edition, by PR Bunker, published in 1979, remains the sole textbook that explains
the use of the molecular symmetry group in understanding high resolution molecular …

▪ Abstract We review stimulated emission pumping as used to study molecular dynamics.
The review presents unimolecular as well as scattering studies. Topics include …

At low energies, molecular vibrational motion is described by the normal modes model. This
model breaks down at higher energy, with strong coupling between normal modes and …

This article reviews recent research on acetylene which is intended as a contribution to the
understanding of intramolecular vibrational energy flow when it is poorly described by either …

We have gathered 122 known experimental data concerning the vibrational energy levels of
acetylene, C2H2, up to 12 000 cm 1. We have fitted the data simultaneously to a model …

The vibrational description of H216O in terms of Morse local oscillators for both bending and
stretching degrees of freedom is presented. Expansions of the kinetic and potential energies …

Using a combination of low resolution dispersed A ̃→ X ̃ fluorescence spectra and high
resolution stimulated emission pumping, we have spectroscopically identified the first stages …

We investigate the large-amplitude bending dynamics of acetylene, in its ground electronic
state, using an effective Hamiltonian model that reproduces all relevant experimental data …

All 253 vibrational levels in the ground electronic state of 12C2H2 with assigned rotational
structure reported in the literature from absorption, stimulated emission pumping, and …

The efficiency and insight of global, polyad-based modeling in overtone spectroscopy and
dynamics is demonstrated. Both vibration and vibration–rotation polyads are considered …