A close look at molecular self-assembly with the transmission electron microscope

A Rizvi, JT Mulvey, BP Carpenter, R Talosig… - Chemical …, 2021 - ACS Publications
Molecular self-assembly is pervasive in the formation of living and synthetic materials.
Knowledge gained from research into the principles of molecular self-assembly drives …

[HTML][HTML] An overview of coacervates: The special disperse state of amphiphilic and polymeric materials in solution

SP Moulik, AK Rakshit, A Pan, B Naskar - Colloids and Interfaces, 2022 - mdpi.com
Individual amphiphiles, polymers, and colloidal dispersions influenced by temperature, pH,
and environmental conditions or interactions between their oppositely charged pairs in …

Protein-mimetic self-assembly with synthetic macromolecules

MH Barbee, ZM Wright, BP Allen, HF Taylor… - …, 2021 - ACS Publications
Protein-mimetic amphiphiles have significant promise as a platform to access the complex
functions of natural biological materials and incorporate the tunability and environmental …

[HTML][HTML] Recent Advances in Coacervation and Underlying Noncovalent Molecular Interaction Mechanisms

Q Peng, T Wang, D Yang, X Peng, H Zhang… - Progress in Polymer …, 2024 - Elsevier
Coacervation is a liquid-liquid phase separation phenomenon. It involves the formation of a
dense coacervate phase, rich in concentrated materials, and a co-existing immiscible dilute …

Observation of liquid–liquid-phase separation and vesicle spreading during supported bilayer formation via liquid-phase transmission electron microscopy

A Rizvi, JT Mulvey, JP Patterson - Nano Letters, 2021 - ACS Publications
Liquid-phase transmission electron microscopy (LP-TEM) enables the real-time visualization
of nanoscale dynamics in solution. This technique has been used to study the formation and …

Ouzo effect examined at the nanoscale via direct observation of droplet nucleation and morphology

MA Vratsanos, W Xue, ND Rosenmann… - ACS Central …, 2023 - ACS Publications
Herein, we present the direct observation via liquid-phase transmission electron microscopy
(LPTEM) of the nucleation and growth pathways of structures formed by the so-called “ouzo …

The intermediate water concept for pioneering polymeric biomaterials: A review and update

S Nishimura, M Tanaka - Bulletin of the Chemical Society of …, 2023 - academic.oup.com
Polymeric biomaterials are often used in water and hydration water molecules with different
mobilities, such as non-freezing water, intermediate water, and free water, are formed on …

Selective accumulation to tumor cells with coacervate droplets formed from a water-insoluble acrylate polymer

K Nishida, S Nishimura, M Tanaka - Biomacromolecules, 2022 - ACS Publications
Selective targeting of specific cells without the use of biological ligands has not been
achieved. In the present study, we revealed that the coacervate droplets formed from poly (2 …

Exploration of Organic Nanomaterials with Liquid-Phase Transmission Electron Microscopy

J Korpanty, NC Gianneschi - Accounts of chemical research, 2023 - ACS Publications
Conspectus Organic, soft materials with solution-phase nanoscale structures, such as
emulsions, hydrogels, and thermally responsive materials, are inherently difficult to directly …

Formation kinetics of polymer vesicles from spherical and cylindrical micelles bearing the polyelectrolyte complex core studied by time-resolved USAXS and SAXS

R Takahashi, T Narayanan, S Yusa, T Sato - Macromolecules, 2022 - ACS Publications
Polymer vesicles (polymersomes) have received considerable attention in the last several
decades, but little has been known about the kinetics of the formation process, despite their …