Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Metal-catalysed C–Het (F, O, S, N) and C–C bond arylation

B Zhao, T Rogge, L Ackermann, Z Shi - Chemical Society Reviews, 2021 - pubs.rsc.org
The formation of C–aryl bonds has been the focus of intensive research over the last
decades for the construction of complex molecules from simple, readily available feedstocks …

Visible‐light‐induced decarboxylative functionalization of carboxylic acids and their derivatives

J Xuan, ZG Zhang, WJ Xiao - … Chemie International Edition, 2015 - Wiley Online Library
Visible‐light‐induced radical decarboxylative functionalization of carboxylic acids and their
derivatives has recently received considerable attention as a novel and efficient method to …

[HTML][HTML] Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Direct C− H transformation via iron catalysis

CL Sun, BJ Li, ZJ Shi - Chemical Reviews, 2011 - ACS Publications
The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Direct aldehyde C–H arylation and alkylation via the combination of nickel, hydrogen atom transfer, and photoredox catalysis

X Zhang, DWC MacMillan - Journal of the American Chemical …, 2017 - ACS Publications
A mechanism that enables direct aldehyde C–H functionalization has been achieved via the
synergistic merger of photoredox, nickel, and hydrogen atom transfer catalysis. This mild …

Acyl radical chemistry via visible-light photoredox catalysis

A Banerjee, Z Lei, MY Ngai - Synthesis, 2019 - thieme-connect.com
Visible-light photoredox catalysis enables easy access to acyl radicals under mild reaction
conditions. Reactive acyl radicals, generated from various acyl precursors such as …

Decarboxylative coupling reactions: a modern strategy for C–C-bond formation

N Rodríguez, LJ Goossen - Chemical Society Reviews, 2011 - pubs.rsc.org
This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling

S Ahn, M Hong, M Sundararajan, DH Ess… - Chemical …, 2019 - ACS Publications
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …

Merging photoredox and nickel catalysis: The direct synthesis of ketones by the decarboxylative arylation of α‐oxo acids

L Chu, JM Lipshultz… - Angewandte Chemie …, 2015 - Wiley Online Library
The direct decarboxylative arylation of α‐oxo acids has been achieved by synergistic visible‐
light‐mediated photoredox and nickel catalysis. This method offers rapid entry to aryl and …