Halogen radical oxidants in natural and engineered aquatic systems

K Zhang, KM Parker - Environmental science & technology, 2018 - ACS Publications
Photochemical reactions contribute to the transformation of contaminants and
biogeochemically important substrates in environmental aquatic systems. Recent research …

Iodine transfers in the coastal marine environment: the key role of brown algae and of their vanadium-dependent haloperoxidases

C Leblanc, C Colin, A Cosse, L Delage, S La Barre… - Biochimie, 2006 - Elsevier
Brown algal kelp species are the most efficient iodine accumulators among all living
systems, with an average content of 1.0% of dry weight in Laminaria digitata, representing a …

Halogens and their role in polar boundary-layer ozone depletion

WR Simpson, R Von Glasow, K Riedel… - Atmospheric …, 2007 - acp.copernicus.org
During springtime in the polar regions, unique photochemistry converts inert halide salt ions
(eg Br−) into reactive halogen species (eg Br atoms and BrO) that deplete ozone in the …

Tropospheric halogen chemistry

R von Glasow, PJ Crutzen - Treatise on Geochemistry, 2003 - ui.adsabs.harvard.edu
Halogens are very reactive chemicals that are known to play an important role in
anthropogenic stratospheric ozone depletion chemistry, first recognized by Molina and …

Bromine contamination and risk management in terrestrial and aquatic ecosystems

AC Leri, O Hettithanthri, S Bolan, T Zhang… - Journal of Hazardous …, 2024 - Elsevier
Bromine (Br) is widely distributed through the lithosphere and hydrosphere, and its
chemistry in the environment is affected by natural processes and anthropogenic activities …

Simultaneous Oxidation of Bromide and Dissolution of Manganese Oxide Induced by Freezing

Y Wu, H Wang, J Du, Y Hu, Q Wu, W Guo… - … Science & Technology, 2024 - ACS Publications
This study demonstrates that the oxidation of bromide by birnessite (δ-MnO2) results in the
concurrent production of soluble manganese (Mn (II)) and reactive bromine (RBr) species in …

Sunlight-driven photochemical halogenation of dissolved organic matter in seawater: a natural abiotic source of organobromine and organoiodine

JD Méndez-Díaz, KK Shimabuku, J Ma… - … science & technology, 2014 - ACS Publications
Reactions of dissolved organic matter (DOM) with photochemically generated reactive
halogen species (RHS) may represent an important natural source of organohalogens …

MnO2-Induced Oxidation of Iodide in Frozen Solution

J Du, K Kim, S Son, D Pan, S Kim… - Environmental Science & …, 2023 - ACS Publications
Metal oxides play a critical role in the abiotic transformation of iodine species in natural
environments. In this study, we investigated iodide oxidation by manganese dioxides (β …

A new source of volatile organoiodine compounds in surface seawater

M Martino, GP Mills, J Woeltjen… - Geophysical Research …, 2009 - Wiley Online Library
Volatile organoiodine compounds (VOIs) are the main carrier of iodine from the oceans to
the atmosphere. We have identified a novel, sea‐surface source of the short‐lived VOIs …

Observations of iodine monoxide columns from satellite

A Schönhardt, A Richter, F Wittrock… - Atmospheric …, 2008 - acp.copernicus.org
Iodine species in the troposphere are linked to ozone depletion and new particle formation.
In this study, a full year of iodine monoxide (IO) columns retrieved from measurements of the …