A highly dynamic covalent polymer network without creep: mission impossible?
F Van Lijsebetten, T Debsharma… - Angewandte Chemie …, 2022 - Wiley Online Library
Dynamic covalent polymer networks provide an interesting solution to the challenging
recyclability of thermosets and elastomers. One of the remaining design constraints …
recyclability of thermosets and elastomers. One of the remaining design constraints …
X‐yne click polymerization
X Fu, A Qin, BZ Tang - Aggregate, 2023 - Wiley Online Library
Alkyne‐based click polymerizations have been nurtured into a powerful synthetic technique
for the preparation of new polymers with advanced structures and versatile properties …
for the preparation of new polymers with advanced structures and versatile properties …
Epoxy adhesives with reversible hardeners: controllable thermal debonding in bulk and at interfaces
F Van Lijsebetten, T Maiheu, JM Winne… - Advanced …, 2023 - Wiley Online Library
On‐demand adhesive dismantling has the potential to improve multimaterial product
recycling, but its implementation has been hampered by a critical trade‐off between strong …
recycling, but its implementation has been hampered by a critical trade‐off between strong …
Thermally latent bases in dynamic covalent polymer networks and their emerging applications
D Reisinger, MU Kriehuber, M Bender… - Advanced …, 2023 - Wiley Online Library
A novel strategy allowing temporal control of dynamic bond exchange in covalently
crosslinked polymer networks via latent transesterification catalysts is introduced. Obtained …
crosslinked polymer networks via latent transesterification catalysts is introduced. Obtained …
Closed‐Loop Recycling of Vinylogous Urethane Vitrimers
Y Ma, X Jiang, Z Shi, JA Berrocal… - Angewandte Chemie …, 2023 - Wiley Online Library
Devising energy‐efficient strategies for the depolymerization of plastics and the recovery of
their structural components in high yield and purity is key to a circular plastics economy …
their structural components in high yield and purity is key to a circular plastics economy …
Characterising different molecular landscapes in dynamic covalent networks
F Van Lijsebetten, K De Bruycker… - Chemical …, 2022 - pubs.rsc.org
Dynamic covalent networks present a unique opportunity to exert molecular-level control on
macroscopic material properties, by linking their thermal behaviour to the thermodynamics …
macroscopic material properties, by linking their thermal behaviour to the thermodynamics …
Blocked Phosphates as Photolatent Catalysts for Dynamic Photopolymer Networks
C Dertnig, G Guedes de la Cruz… - Angewandte Chemie …, 2023 - Wiley Online Library
While latent catalysts are a well‐established strategy for initiating and controlling the rate of
polymerization reactions, their use in dynamic polymer networks is still in its infancy. The …
polymerization reactions, their use in dynamic polymer networks is still in its infancy. The …
N-Sulfonyl Urethanes to Design Polyurethane Networks with Temperature-Controlled Dynamicity
S Maes, F Van Lijsebetten, JM Winne… - Macromolecules, 2023 - ACS Publications
(Re) processing of cross-linked polyurethanes (PUs) is often energy intensive and inefficient
since dissociation of urethane linkages at elevated temperatures generates highly reactive …
since dissociation of urethane linkages at elevated temperatures generates highly reactive …
Covalent Adaptable Networks Made by Reactive Processing of Highly Entangled Polymer: Synthesis-Structure-Thermomechanical Property-Reprocessing …
Reactive processing provides a simple approach for grafting dynamic covalent cross-linkers
onto linear or branched polymers, resulting in covalent adaptable networks (CANs). We …
onto linear or branched polymers, resulting in covalent adaptable networks (CANs). We …
From Lignins to Renewable Aromatic Vitrimers based on Vinylogous Urethane
During the two last decades, covalent adaptable networks (CANs) have proven to be an
important new class of polymer materials combining the main advantages of thermoplastics …
important new class of polymer materials combining the main advantages of thermoplastics …