Reactions of acetylenes in superbasic media. Recent advances
BA Trofimov, EY Schmidt - Russian Chemical Reviews, 2014 - iopscience.iop.org
The main advances in the chemistry of acetylene in superbasic media achieved over the last
five years are analyzed. Particular emphasis is placed on the ethynylation of aldehydes and …
five years are analyzed. Particular emphasis is placed on the ethynylation of aldehydes and …
Quantum‐chemical models of KOH(KOBut)/DMSO superbasic systems and mechanisms of base‐promoted acetylene reactions
NM Vitkovskaya, VB Orel, VB Kobychev… - … Journal of Quantum …, 2020 - Wiley Online Library
The mechanisms of fundamental base‐promoted acetylene reactions, namely, nucleophilic
addition to the triple C≡ C bond (vinylation) and nucleophilic addition of acetylenic …
addition to the triple C≡ C bond (vinylation) and nucleophilic addition of acetylenic …
Exploring acetylene chemistry in superbasic media: A theoretical study of the effect of water on vinylation and ethynylation reactions with acetylene in KOH/DMSO and …
NM Vitkovskaya, VB Orel, VB Kobychev… - Journal of Physical …, 2017 - Wiley Online Library
A rapidly developing approach adding new dimensions to acetylene chemistry relying on
employment of high basicity media such as alkali metal hydroxide suspensions in dimethyl …
employment of high basicity media such as alkali metal hydroxide suspensions in dimethyl …
Реакции ацетиленов в суперосновных средах-итоги последних лет
БА Трофимов, ЕЮ Шмидт - Успехи химии, 2014 - elibrary.ru
Проанализированы основные итоги развития химии ацетилена в суперосновных
средах за последние пять лет. Особое внимание уделено реакциям этинилирования …
средах за последние пять лет. Особое внимание уделено реакциям этинилирования …
Cascade assembly of 4, 5, 6, 7-tetrahydroindole from cyclohexanone oxime and acetylene in the KOH/DMSO superbase medium: a quantum chemical study
AS Bobkov, NM Vitkovskaya… - The Journal of Organic …, 2020 - ACS Publications
Pyrrole synthesis from ketoximes and acetylene in the KOH/dimethyl sulfoxide (DMSO)
superbase medium (here abbreviated as the KOA reaction) provided access to a wide …
superbase medium (here abbreviated as the KOA reaction) provided access to a wide …
Transition-Metal-Free C-Vinylation of Ketones with Acetylenes: A Quantum-Chemical Rationalization of Similarities and Differences in Catalysis by Superbases MOH …
VB Orel, NM Vitkovskaya, VB Kobychev… - The Journal of …, 2018 - ACS Publications
Transition-metal-free C-vinylation of acetone with phenylacetylene catalyzed by superbases
MOH/DMSO and t BuOM/DMSO (M= Na, K) has been theoretically evaluated in the B3LYP/6 …
MOH/DMSO and t BuOM/DMSO (M= Na, K) has been theoretically evaluated in the B3LYP/6 …