In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

Thiyl radicals have been used by nature in a broad range of biochemical processes. For
instance, thiol residues play an important role in many enzymatic processes as illustrated by …

Photochemical reactions are a key method to generate radical intermediates. Often under
these conditions no toxic reagents are necessary. During recent years, photo-redox catalytic …

The first highly enantioselective catalytic protocol for the reductive coupling of ketones and
hydrazones is reported. These reactions proceed through neutral ketyl radical intermediates …

The first gold‐catalyzed photoredox C (sp2)− H difluoroalkylation and perfluoroalkylation of
hydrazones with readily available RF− Br reagents is reported. The resulting gem …

α-Tertiary amines are a common motif in pharmaceutically important molecules but are
challenging to prepare using asymmetric catalysis. Here, we demonstrate engineered flavin …

A visible-light-initiated α-perfluoroalkyl-β-heteroarylation of various alkenes with
perfluoroalkyl iodides and quinoxalin-2 (1 H)-ones is presented. This three-component …

In recent years, visible‐light‐induced C− H bond functionalization has become an emerging
field at the forefront of organic chemistry. In a general sense, these approaches rely on the …

The ubiquity of tertiary alkylamines in pharmaceutical and agrochemical agents, natural
products and small-molecule biological probes, has stimulated efforts towards their …