Photocontrolled RAFT polymerization: past, present, and future
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …
The mechanochemical synthesis of polymers
A Krusenbaum, S Grätz, GT Tigineh… - Chemical Society …, 2022 - pubs.rsc.org
Mechanochemistry–the utilization of mechanical forces to induce chemical reactions–is a
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …
rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced …
A comparison of RAFT and ATRP methods for controlled radical polymerization
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer
radical polymerization (ATRP) are the two most common controlled radical polymerization …
radical polymerization (ATRP) are the two most common controlled radical polymerization …
Linear block copolymer synthesis
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
Recent developments and future challenges in controlled radical polymerization: a 2020 update
This perspective summarizes the latest exciting developments in controlled radical
polymerization during the last decade (2010–2020). Our focus is to critically highlight …
polymerization during the last decade (2010–2020). Our focus is to critically highlight …
Polymeric delivery of therapeutic nucleic acids
R Kumar, CF Santa Chalarca, MR Bockman… - Chemical …, 2021 - ACS Publications
The advent of genome editing has transformed the therapeutic landscape for several
debilitating diseases, and the clinical outlook for gene therapeutics has never been more …
debilitating diseases, and the clinical outlook for gene therapeutics has never been more …
Bulk depolymerization of poly (methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer
We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …
lower temperatures than previously reported methods through the incorporation of …
Reversing RAFT polymerization: near-quantitative monomer generation via a catalyst-free depolymerization approach
The ability to reverse controlled radical polymerization and regenerate the monomer would
be highly beneficial for both fundamental research and applications, yet this has remained …
be highly beneficial for both fundamental research and applications, yet this has remained …
Photo‐iniferter RAFT polymerization
M Hartlieb - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Light‐mediated polymerization techniques offer distinct advantages over polymerization
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …
reactions fueled by thermal energy, such as high spatial and temporal control as well as the …
Rapid high‐resolution 3D printing and surface functionalization via type I photoinitiated RAFT polymerization
RAFT facilitated digital light projection 3D printing of polymeric materials provides a
convenient and facile route for inducing post‐fabrication transformations via reactivation of …
convenient and facile route for inducing post‐fabrication transformations via reactivation of …