Structure and properties of high-density polymer brushes prepared by surface-initiated living radical polymerization

Y Tsujii, K Ohno, S Yamamoto, A Goto… - … -initiated polymerization I, 2006 - Springer
Surface modifications by polymers are becoming increasingly important for various
applications ranging from biotechnology to advanced microelectronics. Recent successful …

Polymer brushes on flat and curved surfaces: How computer simulations can help to test theories and to interpret experiments

K Binder, A Milchev - Journal of Polymer Science Part B …, 2012 - Wiley Online Library
Theoretical descriptions of static properties of polymer brushes are reviewed, with an
emphasis on monodisperse macromolecules grafted to planar, cylindrical, or spherical …

Environmentally responsive “hairy” nanoparticles: Mixed homopolymer brushes on silica nanoparticles synthesized by living radical polymerization techniques

D Li, X Sheng, B Zhao - Journal of the American Chemical Society, 2005 - ACS Publications
This article reports on the preparation of environmentally responsive “hairy” nanoparticles by
growth of mixed poly (tert-butyl acrylate)(P t BA)/polystyrene (PS) brushes from silica …

Mixed polymer brush-grafted particles: a new class of environmentally responsive nanostructured materials

B Zhao, L Zhu - Macromolecules, 2009 - ACS Publications
Mixed polymer brush-grafted particles, in which two distinct polymers are randomly or
alternately immobilized by one end via a covalent bond on the surface of core particles with …

Synthesis of adaptive polymer brushes via “grafting to” approach from melt

S Minko, S Patil, V Datsyuk, F Simon, KJ Eichhorn… - Langmuir, 2002 - ACS Publications
We report a simple method to synthesize binary polymer brushes from two incompatible
polymers of different polarity. The synthetic route is based on a subsequent step-by-step …

Grafting on solid surfaces:“grafting to” and “grafting from” methods

S Minko - Polymer surfaces and interfaces: characterization …, 2008 - Springer
The grafting of polymer brushes to a solid surface provides a versatile tool for surface
modification and functionalization. End-functionalized polymer chains may be grafted to the …

Lateral versus perpendicular segregation in mixed polymer brushes

S Minko, M Müller, D Usov, A Scholl, C Froeck… - Physical review …, 2002 - APS
Grafting of incompatible polymers on a substrate prevents macrophase separation and the
chains self-assemble laterally. Mixed brushes are exposed to different solvents and the …

Reorganization of binary polymer brushes: Reversible switching of surface microstructures and nanomechanical properties

M Lemieux, D Usov, S Minko, M Stamm… - …, 2003 - ACS Publications
For a binary polymer brush layer, we investigated the morphological state, the structure
reordering, and the nanomechanical properties as a function of treatment with selective …

Chemical Gating with Nanostructured Responsive Polymer Brushes: Mixed Brush versus Homopolymer Brush

M Motornov, R Sheparovych, E Katz, S Minko - Acs Nano, 2008 - ACS Publications
In this report, we describe a novel approach to create an electrochemical gating system
using mixed polymer brushes grafted to an electrode surface, and we explore the switchable …

Phase diagram of a mixed polymer brush

M Müller - Physical Review E, 2002 - APS
We investigate the structure and phase behavior of a two-component (binary) polymer brush
in a solvent within self-consistent field theory as a function of the chains' stretching, the …