The development of practical and efficient methods for C–C and C–X bond formation has
attracted a great deal of current attention with the advent of C–H functionalization reactions …

α-Imino esters are useful precursors for the synthesis of a variety of types of natural and
unnatural α-amino acid derivatives, with a wide range of biological activities. Due to the …

An electrochemically initiated heteroaryltrifluoromethylation of allylic amines was developed.
The cascade reaction involved the anodic oxidation of Langlois reagent (CF3SO2Na) to …

Heterocycles are a ubiquitous substructure in organic small molecules designed for use in
materials and medicines. Recent work in catalysis has focused on enabling access to new …

Quinolines and their derivatives have always been promising leads for drug discovery,
material applications and designing new catalysts. In the past decade, C (sp3)‐H …

We report a mild palladium-catalyzed method for the selective allylation of 4-alkylpyridines
in which highly basic pyridylic anions behave as soft nucleophiles. This method exploits …

Abstract Highly regio‐and diastereoselective 1, 2‐addition of organolithium reagents to
chiral fluoroalkyl α, β‐unsaturated N‐tert‐butanesulfinyl ketimines was developed, providing …

A zinc-catalyzed C (sp3)–H addition of 2-alkylazaarenes to α-keto amides to furnish
azaarene incorporated α-hydroxy amides has been developed with a wide range of …

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An efficient and green approach for the sp3 C–H bond functionalization of 2-methyl
azaarenes to 3-methyl-4-nitro-5-styrylisoxazoles in water has been described …