The coherence and dephasing of vibrational motions of molecules constitute an integral part
of chemical dynamics, influence material properties and underpin schemes to control …

We present an overview of experimental and theoretical investigations exploring the
dynamical evolution of Rydberg-to-valence character in the electronically excited states of …

Processes that proceed in femtoseconds are usually referred to as being ultrafast, and they
are investigated in experiments that involve laser pulses with femtosecond duration in so …

We exploit the phenomenon of resonant dispersive wave (RDW) emission in gas-filled
hollow capillary fibres (HCFs) to realize time-resolved photoelectron imaging (TRPEI) …

2-Nitrotoluene (2-NT) is a good model for both photolabile protecting groups for organic
synthesis and the military explosive 2, 4, 6-trinitrotoluene (TNT). In addition to the direct C …

Time-resolved photoelectron imaging and supporting ab initio quantum chemistry
calculations were used to investigate non-adiabatic excess energy redistribution dynamics …

A series of pyrazol‐derived thiosemicarbazone ligands (L1–L4) were synthesized and
reacted with [Ru (p‐cymene)(μ‐Cl) Cl] 2 to yield a series of “piano‐stool”‐type binuclear …

Laser-based experiments facilitate numerous strategies for interrogating the complex non-
adiabatic dynamics operating in the excited states of molecules. Measurements may be …

Using vacuum-ultraviolet time-resolved velocity map imaging of photoelectrons, we study
ultrafast coupled electronic and nuclear dynamics in low-lying Rydberg states of ammonia …

We report the time-resolved observation of the ultrafast dissociation of the 3p Rydberg state
manifold of nitromethane, which decays with a time constant of 53±5 fs. We access this …