Kinetic Study of Gas-Phase Reactions of Pyruvic Acid with HO2

JR Church, V Vaida, RT Skodje - The Journal of Physical …, 2021 - ACS Publications
Gas-phase reactions between pyruvic acid (PA) and HO2 radicals were examined using ab
initio quantum chemistry and transition state theory. The rate coefficients were determined …

Double Hydrogen-Atom Exchange Reactions of HX (X = F, Cl, Br, I) with HO2

JR Church, RT Skodje - The Journal of Physical Chemistry A, 2018 - ACS Publications
A novel double hydrogen atom exchange process, HX+ H′ O2→ H′ X+ HO2 for the
halogen series X= F, Cl, Br, and I, is identified using theoretical methods. These concerted …

A Kinetic Study of Novel Gas-Phase Reaction Pathways for Pyruvic Acid and Hydrogen Halides with HOx Radicals

JR Church - 2018 - search.proquest.com
Abstract Hydroperoxy (HO 2) and hydroxyl (OH) radicals are known to play important roles in
both combustion and atmospheric chemistry. Although less reactive than hydroxyl radicals …