Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Conspectus Aspects of sustainability are playing an increasingly important role for the
development of new synthetic methods. In this context, the combination of asymmetric …

A novel method for the catalytic asymmetric dearomatization by visible‐light‐activated [2+ 2]
photocycloaddition with benzofurans and one example of a benzothiophene is reported …

The synthesis and the design of octahedral stereogenic-at-metal complexes featuring chiral
ligands and their application as chiral catalysts in various asymmetric reactions are …

A new class of chiral iron catalysts is introduced that contains exclusively achiral ligands
with the overall chirality being the result of a stereogenic iron center. Specifically, iron (II) is …

A cyclometalated ruthenium complex with exclusively metal-centered chirality catalyzes the
conversion of diazoketones to chiral flavanones with up to 99% yield and with up to 96% ee …

Chiral β-amino alcohols are important building blocks for the synthesis of drugs, natural
products, chiral auxiliaries, chiral ligands and chiral organocatalysts. The catalytic …

The first example of a chiral osmium catalyst is reported in which the overall chirality
originates exclusively from a stereogenic metal center (metal-centered chirality) with all …

Chiral metal complexes show promise as asymmetric catalysts and optical materials. Chiral-
at-metal complexes composed of achiral ligands have expanded the versatility and …

A new class of bis‐cyclometalated rhodium (III) catalysts containing two inert cyclometalated
6‐tert‐butyl‐2‐phenyl‐2H‐indazole ligands and two labile acetonitriles is introduced. Single …