Interfacial design and functionization on metal electrodes through self-assembled monolayers

D Chen, J Li - Surface Science Reports, 2006 - Elsevier
Self-assembled monolayers (SAMs) provide a convenient, flexible, and simple system with
which to tailor and functionalize the interfacial properties of metal electrodes. The SAMs on …

Ordered assembly and controlled electron transfer of the blue copper protein azurin at gold (111) single-crystal substrates

Q Chi, J Zhang, JET Andersen… - The Journal of Physical …, 2001 - ACS Publications
We have shown that Pseudomonas aeruginosa azurin can be immobilized on alkanethiol
monolayers self-assembled on Au (111). Immobilization is achieved through hydrophobic …

Electronic properties of functional biomolecules at metal/aqueous solution interfaces

J Zhang, Q Chi, AM Kuznetsov… - The Journal of …, 2002 - ACS Publications
Monolayers of molecules, which retain their function in the adsorbed state on solid surfaces,
are important in materials science, analytical detection, and other technology approaching …

Electron transport mediated by peptides immobilized on surfaces

J Juhaniewicz, J Pawlowski… - Israel Journal of Chemistry, 2015 - Wiley Online Library
Electron transfer reactions in proteins and peptides are crucial for biological energy
conversion. Therefore, an important goal of fundamental research is to provide scientific …

The single-molecule conductance and electrochemical electron-transfer rate are related by a power law

E Wierzbinski, R Venkatramani, KL Davis, S Bezer… - Acs Nano, 2013 - ACS Publications
This study examines quantitative correlations between molecular conductances and
standard electrochemical rate constants for alkanes and peptide nucleic acid (PNA) …

The nature of electronic coupling between ferrocene and gold through alkanethiolate monolayers on electrodes: The importance of chain composition, interchain …

AM Napper, H Liu, DH Waldeck - The Journal of Physical …, 2001 - ACS Publications
Cyclic voltammetry was used to measure electron-transfer rate constants of self-assembled
mixed monolayers on gold electrodes formed by coadsorption of a redox-active ferrocene …

Single-component and mixed ferrocene-terminated alkyl monolayers covalently bound to Si (111) surfaces

B Fabre, F Hauquier - The Journal of Physical Chemistry B, 2006 - ACS Publications
Self-assembled ferrocene monolayers covalently bound to monocrystalline Si (111) surfaces
have been prepared from the attachment of an amine-substituted ferrocene derivative to a …

Replacing −CH2CH2– with −CONH– Does Not Significantly Change Rates of Charge Transport through AgTS-SAM//Ga2O3/EGaIn Junctions

MM Thuo, WF Reus, FC Simeone, C Kim… - Journal of the …, 2012 - ACS Publications
This paper describes physical-organic studies of charge transport by tunneling through self-
assembled monolayers (SAMs), based on systematic variations of the structure of the …

Long-range electron transfer through monolayers and bilayers of alkanethiols in electrochemically controlled hg− hg tunneling junctions

RL York, PT Nguyen, K Slowinski - Journal of the American …, 2003 - ACS Publications
The rates of electron tunneling through monolayers and bilayers of alkanethiols self-
assembled in a potentiostatically controlled Hg− Hg junction are reported. An alkanethiolate …

Effects of monolayer structures on long-range electron transfer in helical peptide monolayer

K Takeda, T Morita, S Kimura - The Journal of Physical Chemistry …, 2008 - ACS Publications
Self-assembled monolayers of α-helical peptides were prepared on gold, and the effects of
the monolayer structures (kind of constituent amino acid, molecular orientation, and …