Transition metal‐catalyzed C− H functionalization of diverse arenes with alkyne units has
attracted enormous attention for decades since they provide straightforward access to …

Polycyclic fused indoles are ubiquitous in natural products and pharmaceuticals due to their
immense structural diversity and biological inference, making them suitable for charting …

Herein, we report an acid-controlled highly tunable selectivity of Rh (III)-catalyzed [4+ 2] and
[3+ 3] annulations of N-carboxamide indoles with iodonium ylides lead to form synthetically …

Highly selective and switchable [4+ 2] annulations of 2-arylindoles with iodonium ylides
were achieved by performing solvent-controlled Rh (III)-catalyzed C–H activations. When …

Exploring multistep cascade reactions triggered by C–H activation are recognized as
appealing, yet challenging. Herein, we disclose a Rh (III)-catalyzed domino C–H coupling of …

The transition-metal-catalyzed C–H functionalization of sulfoxonium ylides with alkynes
formally participates in [4+ 2] annulations to deliver the naphthol scaffolds. In contrast, herein …

Co (III)-catalyzed highly regio-and stereoselective direct C6 olefination of 2-pyridones with
alkynes has been developed with the assistance of chelation. Upon variation of the reaction …

Herein, we report the divergent synthesis of alkynylated imidazo [1, 5-a] indoles and α, α-
difluoromethylene tetrasubstituted alkenes through Rh (III)-catalyzed [4+ 1] …

A rhodium-catalyzed diastereoselective formal [5+ 2] annulation of indoles with
cyclohexadienone-containing 1, 6-enynes has been established via indole 2, 3 …

Herein, we disclose an efficient ruthenium-catalyzed C–H functionalization of 2-
arylbenzimidazoles/2-arylimidazoles with iodonium ylides leading to substituted tetracyclic …