Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

The significant progress made in the area of transition metal-catalyzed nitrene transfer into C–
H or CC bonds mediated by iodine (III) oxidants has been translated into many elegant …

Catalyst-controlled, selective nitrene transfer is often challenging when both C–H and C C
bonds are present in a substrate. Interestingly, a simple change in the Ag (I): L ratio (L …

The ring-opening/cyclization of cyclopropane derivatives has drawn great attention in the
past several decades. In this review, recent efforts in the development of oxidative radical …

Azide-methylenecyclopropanes (azide-MCPs) underwent an intermolecular cyclization with
isonitriles catalyzed by a RhII complex to produce a series of pyrrolo [2, 3-b] quinolines in …

N-Mesyloxycarbamates are practical nitrene precursors that undergo C–H amination
reactions in the presence of rhodium dimer catalysts. Under these conditions, both …

The reaction mechanisms and chemoselectivity on the intramolecular allylic C–H amination
versus alkene aziridination of 4-pentenylsulfamate promoted by four elaborately selected …

The ubiquity of nitrogen in life and material sciences makes the search for Csingle bondN
bond-forming reactions a topic of paramount importance in organic chemistry. The direct …