New strategies for the transition-metal catalyzed synthesis of aliphatic amines
A Trowbridge, SM Walton, MJ Gaunt - Chemical reviews, 2020 - ACS Publications
Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …
simple, readily available feedstocks have become a cornerstone of modern synthetic …
Transition metal-catalyzed C–H amination: scope, mechanism, and applications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …
synthetic approach to construct N-functionalized molecules. Over the last few decades …
Advances in synthetic applications of hypervalent iodine compounds
A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …
Transition metal-catalyzed iodine (III)-mediated nitrene transfer reactions: efficient tools for challenging syntheses
B Darses, R Rodrigues, L Neuville… - Chemical …, 2017 - pubs.rsc.org
The significant progress made in the area of transition metal-catalyzed nitrene transfer into C–
H or CC bonds mediated by iodine (III) oxidants has been translated into many elegant …
H or CC bonds mediated by iodine (III) oxidants has been translated into many elegant …
Catalyst-controlled nitrene transfer by tuning metal: ligand ratios: Insight into the mechanisms of chemoselectivity
C Weatherly, JM Alderson, JF Berry, JE Hein… - …, 2017 - ACS Publications
Catalyst-controlled, selective nitrene transfer is often challenging when both C–H and C C
bonds are present in a substrate. Interestingly, a simple change in the Ag (I): L ratio (L …
bonds are present in a substrate. Interestingly, a simple change in the Ag (I): L ratio (L …
Oxidative radical ring-opening/cyclization of cyclopropane derivatives
Y Liu, QL Wang, Z Chen, CS Zhou… - Beilstein journal of …, 2019 - beilstein-journals.org
The ring-opening/cyclization of cyclopropane derivatives has drawn great attention in the
past several decades. In this review, recent efforts in the development of oxidative radical …
past several decades. In this review, recent efforts in the development of oxidative radical …
Rh (II)-Catalyzed formation of pyrrolo [2, 3-b] quinolines from azide-methylenecyclopropanes and isonitriles
K Chen, XY Tang, M Shi - Chemical Communications, 2016 - pubs.rsc.org
Azide-methylenecyclopropanes (azide-MCPs) underwent an intermolecular cyclization with
isonitriles catalyzed by a RhII complex to produce a series of pyrrolo [2, 3-b] quinolines in …
isonitriles catalyzed by a RhII complex to produce a series of pyrrolo [2, 3-b] quinolines in …
Rhodium (II)-catalyzed C–H aminations using N-mesyloxycarbamates: reaction pathway and by-product formation
E Azek, M Khalifa, J Bartholoméüs, M Ernzerhof… - Chemical …, 2019 - pubs.rsc.org
N-Mesyloxycarbamates are practical nitrene precursors that undergo C–H amination
reactions in the presence of rhodium dimer catalysts. Under these conditions, both …
reactions in the presence of rhodium dimer catalysts. Under these conditions, both …
Mechanistic Investigation of Dirhodium-Catalyzed Intramolecular Allylic C–H Amination versus Alkene Aziridination
X Zhang, H Xu, C Zhao - The Journal of Organic Chemistry, 2014 - ACS Publications
The reaction mechanisms and chemoselectivity on the intramolecular allylic C–H amination
versus alkene aziridination of 4-pentenylsulfamate promoted by four elaborately selected …
versus alkene aziridination of 4-pentenylsulfamate promoted by four elaborately selected …
Dirhodium (II)-Catalyzed C (sp3)–H Amination Using Iodine (III) Oxidants
J Buendia, G Grelier, P Dauban - Advances in Organometallic Chemistry, 2015 - Elsevier
The ubiquity of nitrogen in life and material sciences makes the search for Csingle bondN
bond-forming reactions a topic of paramount importance in organic chemistry. The direct …
bond-forming reactions a topic of paramount importance in organic chemistry. The direct …