A comprehensive review on lignin pyrolysis: Mechanism, modeling and the effects of inherent metals in biomass

E Leng, Y Guo, J Chen, S Liu, E Jiaqiang, Y Xue - Fuel, 2022 - Elsevier
This work comprehensively reviews the pyrolysis of lignin from the aspects of mechanism,
modeling, and effects of inorganic species. Initially, the lignin general pyrolysis …

Recent advances in mass spectrometric studies on the reaction process of biomass pyrolysis

P Liu, H Zhuang, Y Qian, J Yang, Y Pan, Z Zhou… - Fuel Processing …, 2022 - Elsevier
Biomass pyrolysis has arisen great attention for producing clean fuels, valuable chemicals,
and advanced materials. Knowledge on the properties of both final products and …

Investigation on reaction mechanism for CO2 gasification of softwood lignin by ReaxFF MD method

Y Pang, X Zhu, N Li, Z Wang - Energy, 2023 - Elsevier
As an important component of biomass, lignin greatly affects the overall conversion
efficiency of biomass. In this paper, the microscopic reaction mechanism for CO 2 …

Mathematical modeling of fast biomass pyrolysis and bio-oil formation. Note II: secondary gas-phase reactions and bio-oil formation

E Ranzi, PEA Debiagi, A Frassoldati - ACS Sustainable Chemistry …, 2017 - ACS Publications
This paper summarizes the research activities done at Politecnico di Milano in the field of the
detailed kinetic modeling of fast pyrolysis of biomass to produce bio-oil. Note I of this work …

Detailed kinetic mechanism of gas-phase reactions of volatiles released from biomass pyrolysis

PEA Debiagi, G Gentile, M Pelucchi, A Frassoldati… - Biomass and …, 2016 - Elsevier
Comprehensive chemical models to describe the behavior of biomass pyrolysis, gasification
and combustion are crucial for the simulation and design of thermochemical processes of …

Mechanistic understanding of thermochemical conversion of polymers and lignocellulosic biomass

X Zhou, LJ Broadbelt, R Vinu - Advances in chemical engineering, 2016 - Elsevier
Pyrolysis is a promising thermochemical technique to convert polymers such as waste
plastics and lignocellulosic biomass to liquid products that are valuable either directly as or …

Cellulose-lignin interactions during fast pyrolysis with different temperatures and mixing methods

S Wu, D Shen, J Hu, H Zhang, R Xiao - Biomass and Bioenergy, 2016 - Elsevier
In this work, interactions between cellulose and lignin during fast pyrolysis were studied to
identify the impact of sample preparation on the light-products distribution. Cellulose-lignin …

Measuring biomass fast pyrolysis kinetics: State of the art

G SriBala, HH Carstensen… - Wiley …, 2019 - Wiley Online Library
Fast pyrolysis of lignocellulosic biomass is considered to be a promising thermochemical
route for the production of drop‐in fuels and valuable chemicals. During the past decades, a …

Catalytic cracking of model compounds of bio-oil: Characteristics and mechanism research on guaiacol and acetic acid

H Zhang, C Yang, Y Tao, M Chen, R Xiao - Fuel Processing Technology, 2022 - Elsevier
The unstable oxygenates of raw bio-oil limit its high-value utilization, which renders the
refinement process necessary. Catalytic cracking is one of the promising refining methods …

Continuous 5-hydroxymethylfurfural production from monosaccharides in a microreactor

Y Muranaka, H Nakagawa, R Masaki… - Industrial & …, 2017 - ACS Publications
5-Hydroxymethylfurfural (HMF) was effectively produced from monosaccharides in a
microreactor. A biphasic reaction system was employed to achieve the immediate extraction …