Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Combining chemistry and protein engineering for new-to-nature biocatalysis
Biocatalysis, the application of enzymes to solve synthetic problems of human import, has
blossomed into a powerful technology for chemical innovation. In the past decade, a …
blossomed into a powerful technology for chemical innovation. In the past decade, a …
Reactions of hydrosilanes with transition metal complexes
JY Corey - Chemical Reviews, 2016 - ACS Publications
This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …
complexes and characterization of the products covers the period 2009 thru 2013. After a …
Accessing zinc monohydride cations through coordinative interactions
We present isolable examples of formal zinc hydride cations supported by N‐heterocyclic
carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) …
carbene (NHC) donors, and investigate the dual electrophilic and nucleophilic (hydridic) …
Zinc hydride-catalyzed hydrofuntionalization of ketones
Three new dimeric bis-guanidinate zinc (II) alkyl, halide, and hydride complexes [LZnEt] 2
(1),[LZnI] 2 (2) and [LZnH] 2 (3) were prepared. Compound 3 was successfully employed for …
(1),[LZnI] 2 (2) and [LZnH] 2 (3) were prepared. Compound 3 was successfully employed for …
Abiotic reduction of ketones with silanes catalysed by carbonic anhydrase through an enzymatic zinc hydride
Enzymatic reactions through mononuclear metal hydrides are unknown in nature, despite
the prevalence of such intermediates in the reactions of synthetic transition-metal catalysts. If …
the prevalence of such intermediates in the reactions of synthetic transition-metal catalysts. If …
A Cationic Zinc Hydride Cluster Stabilized by an N‐Heterocyclic Carbene: Synthesis, Reactivity, and Hydrosilylation Catalysis
The trinuclear cationic zinc hydride cluster [(IMes) 3Zn3H4 (THF)](BPh4) 2 (1) was obtained
either by protonation of the neutral zinc dihydride [(IMes) ZnH2] 2 with a Brønsted acid or by …
either by protonation of the neutral zinc dihydride [(IMes) ZnH2] 2 with a Brønsted acid or by …
Synthesis, Structure, and Reactivity of a Mononuclear Organozinc Hydride Complex: Facile Insertion of CO2 into a Zn–H Bond and CO2-Promoted Displacement of …
W Sattler, G Parkin - Journal of the American Chemical Society, 2011 - ACS Publications
Tris (2-pyridylthio) methane,[Tptm] H, has been employed to synthesize the mononuclear
alkyl zinc hydride complex,[κ3-Tptm] ZnH, which has been structurally characterized by X …
alkyl zinc hydride complex,[κ3-Tptm] ZnH, which has been structurally characterized by X …
H2 Cleavage, Hydride Formation, and Catalytic Hydrogenation of Imines with Zinc Complexes of C5Me5 and N-Heterocyclic Carbenes.
P Jochmann, DW Stephan - … Chemie International Edition, 2013 - search.ebscohost.com
The article presents a study which aims to investigates the reactivity of decamethylzincocene
with various N-heterocyclic carbenes (NHCs) that yields an adduct or a sterically Lewis pair …
with various N-heterocyclic carbenes (NHCs) that yields an adduct or a sterically Lewis pair …
Coordinatively saturated tris (oxazolinyl) borato zinc hydride-catalyzed cross dehydrocoupling of silanes and alcohols
The four-coordinate zinc compound ToMZnH (1, ToM= tris (4, 4-dimethyl-2-oxazolinyl)
phenylborate) catalyzes selective alcoholysis of substituted hydrosilanes. The catalytic …
phenylborate) catalyzes selective alcoholysis of substituted hydrosilanes. The catalytic …