First Detection of C2H5NCO in the ISM and Search of Other Isocyanates towards the G+ 0.693-0.027 Molecular Cloud

LF Rodríguez-Almeida, VM Rivilla… - Astronomy & …, 2021 - aanda.org
Context. Little is known about the chemistry of isocyanates (compounds with the functional
group RN= C= O) in the interstellar medium (ISM), as only four of them have been detected …

A sensitive λ 3 mm line survey of L483-A broad view of the chemical composition of a core around a Class 0 object

M Agúndez, N Marcelino, J Cernicharo… - Astronomy & …, 2019 - aanda.org
An exhaustive chemical characterization of dense cores is mandatory to our understanding
of chemical composition changes from a starless to a protostellar stage. However, only a few …

A rigorous detection of interstellar CH3NCO: An important missing species in astrochemical networks

J Cernicharo, Z Kisiel, B Tercero, L Kolesniková… - Astronomy & …, 2016 - aanda.org
The recent analysis of the composition of the frozen surface of comet 67P/Churyumov-
Gerasimenko has revealed a significant number of complex organic molecules. Methyl …

Laboratory and astronomical discovery of the cyanovinyl radical H2CCCN

C Cabezas, J Tang, M Agúndez, K Seiki… - Astronomy & …, 2023 - aanda.org
We report the first laboratory and interstellar detection of the α-cyano vinyl radical (H 2
CCCN). This species was produced in the laboratory by an electric discharge of a gas …

The role of C/O in nitrile astrochemistry in PDRs and planet-forming disks

R Le Gal, MT Brady, KI Öberg, E Roueff… - The Astrophysical …, 2019 - iopscience.iop.org
Complex nitriles, such as HC 3 N, and CH 3 CN, are observed in a wide variety of
astrophysical environments, including at relatively high abundances in photon-dominated …

The complexity of Orion: An ALMA view-I. Data and first results

L Pagani, C Favre, PF Goldsmith, EA Bergin… - Astronomy & …, 2017 - aanda.org
Context. We wish to improve our understanding of the Orion central star formation region
(Orion-KL) and disentangle its complexity. Aims. We collected data with ALMA during cycle 2 …

Unsaturated dinitriles formation routes in extraterrestrial environments: A combined experimental and theoretical investigation of the reaction between cyano radicals …

D Marchione, L Mancini, P Liang… - The Journal of …, 2022 - ACS Publications
The reaction between cyano radicals (CN, X2Σ+) and cyanoethene (C2H3CN) has been
investigated by a combined approach coupling crossed molecular beam (CMB) experiments …

The N(2D) + CH2CHCN (Vinyl Cyanide) Reaction: A Combined Crossed Molecular Beam and Theoretical Study and Implications for the Atmosphere of Titan

G Vanuzzo, D Marchione, L Mancini… - The Journal of …, 2022 - ACS Publications
The reaction of electronically excited nitrogen atoms, N (2D), with vinyl cyanide, CH2CHCN,
has been investigated under single-collision conditions by the crossed molecular beam …

Detection of interstellar HC4NC and an investigation of isocyanopolyyne chemistry under TMC-1 conditions

C Xue, ER Willis, RA Loomis, KLK Lee… - The Astrophysical …, 2020 - iopscience.iop.org
We report an astronomical detection of HC 4 NC for the first time in the interstellar medium
with the Green Bank Telescope toward the TMC-1 molecular cloud with a minimum …

Low Barrier Methyl Internal Rotations and 14N Quadrupole Coupling in the Microwave Spectrum of 2,4-Dimethylthiazole

S Khemissi, V Van, M Schwell, I Kleiner… - The Journal of …, 2023 - ACS Publications
The microwave spectrum of 2, 4-dimethylthiazole was recorded using a pulsed molecular jet
Fourier-transform microwave spectrometer operating in the frequency range from 2.0 to 26.5 …