Recent advances in the electrochemically mediated chemical transformation of carbon dioxide

ZQ Yu, M Shi - Chemical Communications, 2022 - pubs.rsc.org
CO2 as a classical C1 unit is often used in the synthesis of high value-added carboxylic
acids and their derivatives in organic synthetic chemistry. There have been many reports in …

[HTML][HTML] Direct electrochemical defluorinative carboxylation of α-CF 3 alkenes with carbon dioxide

XT Gao, Z Zhang, X Wang, JS Tian, SL Xie, F Zhou… - Chemical …, 2020 - pubs.rsc.org
An unprecedented γ-carboxylation of α-CF3 alkenes with CO2 is reported. This approach
constitutes a rare example of using electrochemical methods to achieve regioselectivity …

Effects of replacing oxygenated functionality with fluorine on lipophilicity

RJ Glyn, G Pattison - Journal of Medicinal Chemistry, 2021 - ACS Publications
The replacement of oxygenated functionality (hydroxy and alkoxy) with a fluorine atom is a
commonly used bioisosteric replacement in medicinal chemistry. In this paper, we use …

[HTML][HTML] Two-dimensional self-assembly and co-assembly of two tetracarboxylic acid derivatives investigated by STM

X Peng, L Gan, W Zhai, X Chen, K Deng, W Duan… - Nanoscale …, 2023 - pubs.rsc.org
In this work, the two-dimensional self-assembly and co-assembly behaviors of two
tetracarboxylic acid derivatives (H4BDETP and H4BTB) were investigated by scanning …

Determining the relative structural relevance of halogen and hydrogen bonds in self-assembled monolayers

H Pinfold, M Sacchi, G Pattison… - The Journal of Physical …, 2021 - ACS Publications
Although hydrogen bonds have long been established as a highly effective intermolecular
interaction for controlling the formation of self-assembled monolayers, the potential utility of …

Regulation of a porphyrin derivative containing two symmetric benzoic acids by different pyridines

L Ma, P Wang, W Duan, B Tu, Q Zeng - Langmuir, 2021 - ACS Publications
A porphyrin derivative called 5, 15-di (4-carboxyphenyl) porphyrin (H2DCPp) with carboxyl
groups successfully self-assembled on a highly oriented pyrolytic graphite (HOPG) surface …

A Photochromic Thienyl Containing Zinc-Organic Framework with Three-Fold Interpenetrating Arrangement Showing Reversible Switching Photoconducting Property

A Tan, J Zhang, J Piao, J Li, Z Fu - Journal of Inorganic and …, 2023 - Springer
Exploring novel photoconductance switch crystalline materials with color indication is of the
utmost importance. Herein, we reported a photochromic and photoconductive zinc organic …

Transient Formation of Hemiketals from Pentafluoro-gem-diols in the Presence of Alcohols

B Islam, DA Colby - Journal of Fluorine Chemistry, 2023 - Elsevier
Pentafluoro-gem-diols have emerged as a source of reactive intermediates for synthesizing
fluorinated molecules. When pentafluoro-gem-diols were exposed to alcohols as solvents …

From Simple Alkenes and CO2 to Fluorinated Carboxylic Acids: Computational Studies and Predictions

J Echeverría, J Jover - European Journal of Organic Chemistry, 2022 - Wiley Online Library
Fluorinated carboxylic acids may soon become a relevant class of compounds for new
materials development and as synthons in medicinal chemistry. In this report, a potential …

Fluorination as a route towards unlocking the hydrogen bond donor ability of phenolic compounds in self-assembled monolayers

H Pinfold, G Pattison, G Costantini - CrystEngComm, 2020 - pubs.rsc.org
We report on the comparative performance of a simple diphenol and its fluorinated analogue
as hydrogen-bond-donating building blocks for the formation of multicomponent self …