Acetylene is a key building block for organic chemistry and potentially can be involved in a
diverse range of synthetic transformations. However, critical analysis of practical …

Industrially, aldehydes are produced annually on a multimillion-tonne scale via the
hydroformylation of olefins with syngas (CO/H2 mixture). Nonetheless, this transformation …

Fluorine is an increasingly common substituent in pharmaceuticals and agrochemicals
because it improves the bioavailability and metabolic stability of organic molecules …

A phosphine-free, efficient protocol for aminocarbonylation and carbonylative Suzuki–
Miyaura coupling has been developed using a novel palladium complex,[PdII (DMAP) 2 …

In this study, an efficient method for hydrogenation reactions has been reported in a short
reaction time using a two-chamber reactor. This process involves the ex situ generation of …

Herein, we report an approach for generating thionyl fluoride (SOF2) from the commodity
chemicals thionyl chloride (SOCl2) and potassium fluoride (KF). The methodology relies on …

The application of carboxy‐MIDA‐boronate (MIDA= N‐methyliminodiacetic acid) as an in
situ CO surrogate for various palladium‐catalyzed transformations is described. Carboxy …

Herein we report a novel methodology for the ex situ generation of SF5Cl by employing 4,
4′-dipyridyl disulfide as a safe commercial reagent, obviating the need for lecture bottles …

Gases are essential for various applications relevant to human health, including in medicine,
biomedical imaging, and pharmaceutical synthesis. However, gases are significantly more …

Abstract Sulfur (VI)‐fluoride exchange (SuFEx) chemistry, an all‐encompassing term for
substitution events that replace fluoride at an electrophilic sulfur (VI), enables the rapid and …