The biologically relevant coordination chemistry of iron and nitric oxide: electronic structure and reactivity

N Lehnert, E Kim, HT Dong, JB Harland… - Chemical …, 2021 - ACS Publications
Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Opportunities for nitric oxide in potentiating cancer immunotherapy

J Kim, SN Thomas - Pharmacological Reviews, 2022 - ASPET
Despite nearly 30 years of development and recent highlights of nitric oxide (NO) donors
and NO delivery systems in anticancer therapy, the limited understanding of exogenous …

Mechanism of N–N Bond Formation by Transition Metal–Nitrosyl Complexes: Modeling Flavodiiron Nitric Oxide Reductases

C Van Stappen, N Lehnert - Inorganic Chemistry, 2018 - ACS Publications
Nitric oxide (NO) has a number of important biological functions, including nerve signaling
transduction, blood pressure control, and, at higher concentrations, immune defense. A …

Trispyrazolylborate coinage metals complexes: Structural features and catalytic transformations

JM Muñoz-Molina, TR Belderrain, PJ Pérez - Coordination Chemistry …, 2019 - Elsevier
Tris (pyrazolyl) borates (Tp x) have become one of the most broadly used polydentate
anionic ligands in coordination chemistry and catalysis since Trofimenko introduced them in …

T-Shaped Palladium and Platinum {MNO}10 Nitrosyl Complexes

MJG Sinclair, N Roig, MR Gyton, N Tsoureas… - Inorganic …, 2024 - ACS Publications
The synthesis and characterization of a homologous series of T-shaped {MNO} 10 nitrosyl
complexes of the form [M (PR3) 2 (NO)]+(M= Pd, Pt; R= t Bu, Ad) are reported. These …

Recent advances in multinuclear metal nitrosyl complexes

L Li, L Li - Coordination chemistry reviews, 2016 - Elsevier
The coordination chemistry of metal nitrosyls has expanded rapidly in the past decades due
to major advances of nitric oxide and its metal compounds in biology. This review article …

Copper Nitroprusside-Based Electrochemical Sensor for Detection of Tryptophan

P Sunon, T Rattanaumpa, K Phakhunthod… - Journal of Analysis and …, 2023 - Springer
This work presents a novel electrochemical approach for detecting tryptophan through its
interaction with copper nitroprusside, which is synthesized using a simple chemical co …

Synthesis of CoII–NO Complexes and Their Reactivity as a Source of Nitroxyl

MR Walter, SP Dzul, AV Rodrigues… - Journal of the …, 2016 - ACS Publications
Metal-nitroxyl (M–HNO/M–NO–) coordination units are found in denitrification enzymes of
the global nitrogen cycle, and free HNO exhibits pharmacological properties related to …

Preparation and reactivity of a square-planar PNP cobalt (II)–hydrido complex: isolation of the first {Co–NO} 8–hydride

VM Krishnan, HD Arman, ZJ Tonzetich - Dalton Transactions, 2018 - pubs.rsc.org
The synthesis of a square-planar cobalt (II) hydrido complex supported by a pyrrole-based
PNP ligand has been reinvestigated and its reactivity with various small molecules …

A Triad of Highly Reduced, Linear Iron Nitrosyl Complexes: {FeNO}8–10

MJ Chalkley, JC Peters - Angewandte Chemie, 2016 - Wiley Online Library
Given the importance of Fe–NO complexes in both human biology and the global nitrogen
cycle, there has been interest in understanding their diverse electronic structures. Herein a …