Microgels: Old materials with new applications

M Das, H Zhang, E Kumacheva - Annu. Rev. Mater. Res., 2006 - annualreviews.org
▪ Abstract This review describes the most recent progress in the use of polymer
multiresponsive microgels as central components of advanced, functional colloidal …

Microgels by precipitation polymerization: synthesis, characterization, and functionalization

A Pich, W Richtering - Chemical design of responsive microgels, 2011 - Springer
This chapter reviews recent work on the synthesis of aqueous microgel particles by
precipitation polymerization. Precipitation polymerization allows flexible control over …

Small-angle neutron scattering study of structural changes in temperature sensitive microgel colloids

M Stieger, W Richtering, JS Pedersen… - The Journal of chemical …, 2004 - pubs.aip.org
The structure of temperature-sensitive poly (N-isopropylacrylamide) microgels in dilute
suspension was investigated by means of small-angle neutron scattering. A direct modeling …

Temperature, pH, and ionic strength induced changes of the swelling behavior of PNIPAM− poly (allylacetic acid) copolymer microgels

M Karg, I Pastoriza-Santos, B Rodriguez-Gonzalez… - Langmuir, 2008 - ACS Publications
The volume phase transition of colloidal microgels made of N-isopropylacrylamide (NIPAM)
is well-studied and it is known that the transition temperature can be influenced by …

Does Flory–Rehner theory quantitatively describe the swelling of thermoresponsive microgels?

CG Lopez, W Richtering - Soft Matter, 2017 - pubs.rsc.org
The swelling of thermoresponsive microgels is widely modelled through Flory–Rehner
theory, which combines Flory–Huggins solution thermodynamics with the affine network …

[图书][B] Smart polymers: applications in biotechnology and biomedicine

I Galaev, B Mattiasson - 2007 - taylorfrancis.com
The first book to tackle the application of smart polymers in bioseparation and
bioprocessing, Smart Polymers: Applications in Biotechnology and Biomedicine broke new …

Preparation of Monodisperse Poly(N-isopropylacrylamide) Microgel Particles with Homogenous Cross-Link Density Distribution

R Acciaro, T Gilanyi, I Varga - Langmuir, 2011 - ACS Publications
Monodisperse microgel latex with homogeneous cross-link density distribution within the
particles was prepared by feeding the monomer and cross-linker into the reaction mixture in …

Volume phase transition of “smart” microgels in bulk solution and adsorbed at an interface: A combined AFM, dynamic light, and small angle neutron scattering study

S Höfl, L Zitzler, T Hellweg, S Herminghaus, F Mugele - Polymer, 2007 - Elsevier
In the present article the swelling behavior of copolymer microgel particles made of poly (N-
isopropylacrylamide)-co-vinylacetic acid using dynamic light scattering (DLS), neutron …

Kinetic prediction of functional group distributions in thermosensitive microgels

T Hoare, D McLean - The Journal of Physical Chemistry B, 2006 - ACS Publications
A kinetic model accounting for the copolymerization of up to four comonomers is applied to
predict both chain and radial functional group distributions in carboxylic-acid-functionalized …

Mechanically Resistant Poly(N‐vinylcaprolactam) Microgels with Sacrificial Supramolecular Catechin Hydrogen Bonds

E Izak‐Nau, S Braun, A Pich, R Göstl - Advanced Science, 2022 - Wiley Online Library
Microgels (μgels) swiftly undergo structural and functional degradation when they are
exposed to shear forces, which potentially limit their applicability in, eg, biomedicine and …