Ion dissociation in ionic liquids and ionic liquid solutions

O Nordness, JF Brennecke - Chemical reviews, 2020 - ACS Publications
The extent to which cations and anions in ionic liquids (ILs) and ionic liquid solutions are
dissociated is of both fundamental scientific interest and practical importance because ion …

Performance characteristics of lubricants in electric and hybrid vehicles: a review of current and future needs

Y Chen, S Jha, A Raut, W Zhang… - Frontiers in Mechanical …, 2020 - frontiersin.org
Electric and hybrid vehicles are gaining increasing attention in recent years. The
distinguished difference between electric/hybrid vehicles from conventional ones is the …

Spotlight on ionic liquids

EW Castner, JF Wishart - The Journal of chemical physics, 2010 - pubs.aip.org
Ionic liquids are an emerging class of materials with a diverse and extraordinary set of
properties. Understanding the origins of these properties and how they can be controlled by …

Interactions and dynamics in electrolyte solutions by dielectric spectroscopy

R Buchner, G Hefter - Physical Chemistry Chemical Physics, 2009 - pubs.rsc.org
Despite its immense abilities to quantify many aspects of ion–ion and ion–solvent
interactions, dielectric relaxation spectroscopy (DRS) has long been neglected as a tool for …

Electrode polarization and charge transport at solid interfaces

A Serghei, M Tress, JR Sangoro, F Kremer - Physical Review B—Condensed …, 2009 - APS
A quantitative description is suggested for electrode polarization, an ubiquitous
phenomenon which takes place at the interface between a metallic and an ionic conductor …

Effect of molecular weight on the ion transport mechanism in polymerized ionic liquids

F Fan, W Wang, AP Holt, H Feng, D Uhrig, X Lu… - …, 2016 - ACS Publications
The unique properties of ionic liquids (ILs) have made them promising candidates for
electrochemical applications. Polymerization of the corresponding ILs results in a new class …

Dynamics of imidazolium ionic liquids from a combined dielectric relaxation and optical Kerr effect study: evidence for mesoscopic aggregation

DA Turton, J Hunger, A Stoppa, G Hefter… - Journal of the …, 2009 - ACS Publications
We have measured the intermolecular dynamics of the 1, 3-dialkylimidazolium-based room-
temperature ionic liquids (RTILs)[emim][BF4],[emim][DCA], and [bmim][DCA] at 25° C from …

Polymerized ionic liquids: the effect of random copolymer composition on ion conduction

H Chen, JH Choi, D Salas-de la Cruz, KI Winey… - …, 2009 - ACS Publications
Ionic conductivity in new polymerized ionic liquids is of great interest as it applies to solid-
state electrolytes for electrochemical and electromechanical applications. In this study, an …

Relations between the fractional Stokes− Einstein and Nernst− Einstein equations and velocity correlation coefficients in ionic liquids and molten salts

KR Harris - The Journal of Physical Chemistry B, 2010 - ACS Publications
It is often asserted that deviation from the Nernst− Einstein relation (NE) between the molar
conductivity (Λ) and ion self-diffusion coefficients (D i) in ionic liquids (ILs) and molten salts …

Temperature dependence of the dielectric properties and dynamics of ionic liquids

J Hunger, A Stoppa, S Schrödle, G Hefter… - …, 2009 - Wiley Online Library
No solo dancers: The temperature dependence of dielectric spectra suggests that the lower‐
frequency relaxation dominating the dynamics of imidazolium‐based room temperature …