Mononuclear metal–oxygen species, such as metal-superoxo,-peroxo,-hydroperoxo and-
oxo complexes, are key intermediates involved in dioxygen activation and oxidation …

Targeting selective hydroxylation under mild conditions of saturated hydrocarbons has
become a challenging and exciting scientific area that has drawn larger attention in recent …

Researchers have always been intrigued by one-step selective hydroxylation of aromatic
compounds since achieving adequate selectivity toward the target product and avoiding …

Oxo-metal-halide moieties have often been implicated as C–H bond activating oxidants with
the terminal oxo-metal entity identified as the electrophilic oxidant. The electrophilic …

An iron complex with a tetraamido macrocyclic ligand,[(TAML) FeIII]−, was found to be an
efficient and selective catalyst for allylic oxidation of cyclohexene by dioxygen (O2); cyclohex …

Three chiral Schiff base ligands H2L1, H2L2, H2L3 have been synthesized by treating (R)-1,
2-diaminopropane separately with 3, 5-dichlorosalicylaldehyde, 3, 5 …

Redox‐inactive metal ions are one of the most important co‐factors involved in dioxygen
activation and formation reactions by metalloenzymes. In this study, we have shown that the …

A series of Ni (II) complexes of the types [Ni (L)(CH3CN) 2](BPh4) 21–3, 5 and [Ni
(L4)](BPh4) 24, where L= N, N′-bis (2-pyrid-2-ylmethyl)-1, 4-diazepane (L1), N-(6 …

In the last decade, manganese complexes with bis-amino-bis-pyridylmethyl and structurally
related N4 donor ligands have emerged as efficient catalysts of selective epoxidations and …

Molybdenum complexes with ONO tridentate Schiff base ligands based on
salicylideneaminophenolato (SAP) backbone with OH substitution on the salicyl arene ring …