Persistent and stable organic radicals: Design, synthesis, and applications
Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …
incompletely satisfied valency. However, the rapid development of radical chemistry in the …
Near-infrared dyes for two-photon absorption in the short-wavelength infrared: strategies towards optical power limiting
This work provides an overview of the recent advances in the field of two-photon absorbing
chromophores active in the short-wavelength infrared (SWIR) spectral range. Herein the …
chromophores active in the short-wavelength infrared (SWIR) spectral range. Herein the …
Diradicals
M Abe - Chemical Reviews, 2013 - ACS Publications
Open-shell molecules such as radicals, carbenes, and electronically excited-state molecules
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …
exhibit high energies, and thus, in general, they are quite reactive. 1 The short-lived species …
Carbon-based Biradicals: Structural and Magnetic Switching
Sterically hindered C═ C double bonds often deform into a bent or twisted geometry. Thus,
many overcrowded ethylenes or anthraquinodimethanes can adopt multiple conformations …
many overcrowded ethylenes or anthraquinodimethanes can adopt multiple conformations …
Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals
Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
Zethrenes, Extended p-Quinodimethanes, and Periacenes with a Singlet Biradical Ground State
Conspectus Researchers have studied polycyclic aromatic hydrocarbons (PAHs) for more
than 100 years, and most PAHs in the neutral state reported so far have a closed-shell …
than 100 years, and most PAHs in the neutral state reported so far have a closed-shell …
From open-shell singlet diradicaloids to polyradicaloids
In this Feature Article, we highlight our recent efforts toward stable open-shell singlet
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …
Overcrowded Ethylene-Bridged Nanohoop Dimers: Regioselective Synthesis, Multiconfigurational Electronic States, and Global Hückel/Möbius Aromaticity
K Li, Z Xu, J Xu, T Weng, X Chen, S Sato… - Journal of the …, 2021 - ACS Publications
The design and preparation of molecular systems with multiple geometric and electronic
configurations are the cornerstones for multifunctional materials with stimuli-responsive …
configurations are the cornerstones for multifunctional materials with stimuli-responsive …
The electronic applications of stable diradicaloids: present and future
X Hu, W Wang, D Wang, Y Zheng - Journal of Materials Chemistry C, 2018 - pubs.rsc.org
Organic molecules with unpaired electrons are intriguing for advanced applications in
molecular electronics, spintronics and organic batteries, as well as other possible …
molecular electronics, spintronics and organic batteries, as well as other possible …
Recent progress in quinoidal singlet biradical molecules
T Kubo - Chemistry Letters, 2015 - academic.oup.com
Elusive nature in spin state is a feature of singlet biradical molecules and arises from the
weak coupling of unpaired electrons. This highlight review focuses on recent advances in …
weak coupling of unpaired electrons. This highlight review focuses on recent advances in …