Chemical Evolution in Solutions of Ir Complex [H(dmso)2]2[IrCl6]. Structures of [H(dmso)2]2[IrCl6], [H(dmso)][IrCl4(dmso)2], [Me2SCH2C(O)Me][IrCl4(dmso)2], [Me2SCH2C(O) …
OV Rudnitskaya, TA Tereshina… - European Journal of …, 2022 - Wiley Online Library
An iridium complex [H (dmso) 2] 2 [IrCl6](1) is synthesized via the reaction of H2IrCl6 with
DMSO in an acetone solution. The substance is thoroughly characterized using UV‐Vis …
DMSO in an acetone solution. The substance is thoroughly characterized using UV‐Vis …
First Iridium(IV) Chloride–Dimethyl Sulfoxide Complex [H(dmso)2][IrCl5(dmso-κO)]: Synthesis and Structure along with Novel Polymorph Modifications of [H(dmso)2][trans-IrCl4(dmso-κS)2] and [H …
As evidenced by UV–Vis and EPR spectroscopies, the reaction of H2IrCl6· 6H2O or Na2
[IrCl6]· n H2O with DMSO results in a slow reduction of Ir (IV) avoiding the formation of Ir (IV) …
[IrCl6]· n H2O with DMSO results in a slow reduction of Ir (IV) avoiding the formation of Ir (IV) …
Anion‐Directed Conformation Switching and Trigonal Distortion in Hexakis (methylamine) nickel (II) Cations
Abstract The homoleptic [Ni (NH2CH3) 6] 2+ cations have dozens of energetically feasible
conformational isomers (conformers), and we herein show their conformation is tunable …
conformational isomers (conformers), and we herein show their conformation is tunable …
Synthesis and structural characterisation of unprecedented primary N-nitrosamines coordinated to iridium (IV)
The redox chemistry of the N-nitrosamine complexes [IrCl5 (RN (H) NO)] 2–(R= benzyl or n-
butyl) was studied in detail. One-electron oxidations at around 200 mV vs …
butyl) was studied in detail. One-electron oxidations at around 200 mV vs …
Perrhenate and pertechnetate complexes of U (IV), Np (IV), and Pu (IV) with dimethyl sulfoxide as an O-donor ligand
G Andreev, N Budantseva, M Sokolova… - Inorganic …, 2020 - ACS Publications
A series of new dimethyl-sulfoxide-containing pertechnetates and perrhenates of tetravalent
U, Np, and Pu were synthesized and structurally characterized by the X-ray diffractometry. In …
U, Np, and Pu were synthesized and structurally characterized by the X-ray diffractometry. In …
[PDF][PDF] Хлоридодиметилсульфоксидные комплексы осмия и иридия: синтез, строение и свойства
ТА Терёшина - rudn.ru
Актуальность работы. Несмотря на высокую стоимость, платиновые металлы (ПМ) и их
соединения с каждым годом наращивают свое применение во многих областях …
соединения с каждым годом наращивают свое применение во многих областях …
Синтез и кристаллическая структура [Ph4Bi (dmso-O)][IrCl4 (dmso-S) 2]
ВС Сенчурин, ЕП Сырых - Вестник Южно-Уральского …, 2020 - cyberleninka.ru
Взаимодействием гексахлороиридата (III) натрия с нитратом тетрафенилвисмута в
воде с последующей перекристаллизацией из диметилсульфоксида синтезирован …
воде с последующей перекристаллизацией из диметилсульфоксида синтезирован …