Binding and electronic level alignment of π-conjugated systems on metals

A Franco-Cañellas, S Duhm, A Gerlach… - Reports on Progress …, 2020 - iopscience.iop.org
We review the binding and energy level alignment of π-conjugated systems on metals, a
field which during the last two decades has seen tremendous progress both in terms of …

Photons, Excitons, and Electrons in Covalent Organic Frameworks

D Blätte, F Ortmann, T Bein - Journal of the American Chemical …, 2024 - ACS Publications
Covalent organic frameworks (COFs) are created by the condensation of molecular building
blocks and nodes to form two-dimensional (2D) or three-dimensional (3D) crystalline …

Enabling three-dimensional porous architectures via carbonyl functionalization and molecular-specific organic-SERS platforms

I Deneme, G Liman, A Can, G Demirel… - Nature Communications, 2021 - nature.com
Molecular engineering via functionalization has been a great tool to tune noncovalent
intermolecular interactions. Herein, we demonstrate three-dimensional highly crystalline …

From 2D to 3D: bridging self-assembled monolayers to a substrate-induced polymorph in a molecular semiconductor

Y Hao, G Velpula, M Kaltenegger, WR Bodlos… - Chemistry of …, 2022 - ACS Publications
In this study, a new bottom-up approach is proposed to predict the crystal structure of the
substrate-induced polymorph (SIP) of an archetypal molecular semiconductor. In spite of …

Electrostatic interactions shape molecular organization and electronic structure of organic semiconductor blends

G D'avino, S Duhm, RG Della Valle… - Chemistry of …, 2020 - ACS Publications
Halogenation of conjugated molecules represents a powerful approach to tune the
electronic structure of molecular thin films through inductive effects and long-range …

Fabrication and characterization of perovskite type solar cells using phthalocyanine complexes

A Suzuki, H Okumura, Y Yamasaki, T Oku - Applied Surface Science, 2019 - Elsevier
Perovskite compound-based solar cells using metal free phthalocyanine, silicon
phthalocyanine or germanium naphthalocyanine complexes were fabricated and …

Metal screening effect on energy levels at metal/organic interface: Precise determination of screening energy using photoelectron and inverse-photoelectron …

T Aihara, SA Abd-Rahman, H Yoshida - Physical Review B, 2021 - APS
The energy level alignment at the metal/organic interface greatly affects the charge
injection/extraction efficiency of electrodes in organic semiconductor devices. The charge …

Single-molecule junction spontaneously restored by DNA zipper

T Harashima, S Fujii, Y Jono, T Terakawa… - Nature …, 2021 - nature.com
The electrical properties of DNA have been extensively investigated within the field of
molecular electronics. Previous studies on this topic primarily focused on the transport …

S = 1/2 Chain in BiVO3F: Spin Dimers versus Photoanodic Properties

O Mentré, MA Juárez-Rosete, S Saitzek… - Journal of the …, 2021 - ACS Publications
BiVO3F was prepared, characterized, and identified as a unique example of bismuth
vanadyl oxyhalide with paramagnetic V4+ centers. Its crystal structure shows 1D magnetic …

Tailoring van der Waals interactions in ultra-thin two dimensional metal–organic frameworks (MOFs) for photoconductive applications

D Dell'Angelo, I Karamanis, MR Saeb… - Physical Chemistry …, 2024 - pubs.rsc.org
The diverse structural tunability of 2-dimensional π-stacked layered metal–organic
frameworks (2D MOFs) enables the control of charge carrier mobility to achieve specific …