Cyclopolymerizations: Synthetic tools for the precision synthesis of macromolecular architectures

D Pasini, D Takeuchi - Chemical reviews, 2018 - ACS Publications
Monomers possessing two functionalities suitable for polymerization are often designed and
utilized in syntheses directed to the formation of cross-linked macromolecules. In this review …

Recent advances in alkyne-based click polymerizations

D Huang, Y Liu, A Qin, BZ Tang - Polymer Chemistry, 2018 - pubs.rsc.org
Click chemistry, with remarkable advantages such as high efficiency, atom economy, mild
reaction conditions, very high yield, regio-and/or stereoselectivity, and good functionality …

A versatile approach for the synthesis of degradable polymers via controlled ring-opening metathesis copolymerization

JD Feist, DC Lee, Y Xia - Nature Chemistry, 2022 - nature.com
Norbornene derivatives (NBEs) are common monomers for living ring-opening metathesis
polymerization and yield polymers with low dispersities and diverse functionalities …

A general approach to sequence-controlled polymers using macrocyclic ring opening metathesis polymerization

WR Gutekunst, CJ Hawker - Journal of the American Chemical …, 2015 - ACS Publications
A new and general strategy for the synthesis of sequence-defined polymers is described that
employs relay metathesis to promote the ring opening polymerization of unstrained …

Bimolecular Coupling in Olefin Metathesis: Correlating Structure and Decomposition for Leading and Emerging Ruthenium− Carbene Catalysts

DL Nascimento, M Foscato, G Occhipinti… - Journal of the …, 2021 - ACS Publications
Bimolecular catalyst decomposition is a fundamental, long-standing challenge in olefin
metathesis. Emerging ruthenium–cyclic (alkyl)(amino) carbene (CAAC) catalysts, which …

Polypentenamer renaissance: challenges and opportunities

WJ Neary, JG Kennemur - ACS Macro Letters, 2018 - ACS Publications
This Viewpoint highlights the viability and increasing variety of functionalized
polypentenamers as unique and valuable materials created through enthalpy-driven ring …

Controlled Living Cascade Polymerization To Make Fully Degradable Sugar-Based Polymers from d-Glucose and d-Galactose

A Bhaumik, GI Peterson, C Kang… - Journal of the American …, 2019 - ACS Publications
Monomers derived from glucose and galactose, which contain an endocyclic alkene (in the
sugar ring) and a terminal alkyne, underwent a cascade polymerization to prepare new …

Morphologically tunable square and rectangular nanosheets of a simple conjugated homopolymer by changing solvents

S Yang, SY Kang, TL Choi - Journal of the American Chemical …, 2019 - ACS Publications
Two-dimensional (2D) polymer nanosheets have been attracting immense attention owing
to their potential applications in optical devices, membranes, and catalysis. However …

[2+ 2] cycloadditions with an iron carbene: a critical step in enyne metathesis

MR Hoffbauer, VM Iluc - Journal of the American Chemical …, 2021 - ACS Publications
Ruthenium carbenes, famously used in olefin metathesis, have impacted numerous
research areas, ranging from synthesis to materials and biology. Although in the same group …

Kinetically Controlled Preparation of Worm-like Micelles with Tunable Diameter/Length and Structural Stability

W Hou, X Yin, Y Zhou, Z Zhou, Z Liu, J Du… - Journal of the …, 2024 - ACS Publications
Anisotropic nanoparticles such as worm-like micelles have aroused much attention due to
their promising applications from templates to drug delivery. The fabrication of worm-like …