The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …

Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

The exploitation of highly efficient carbon dioxide reduction (CO2RR) electrocatalyst for
methane (CH4) electrosynthesis has attracted great attention for the intermittent renewable …

The emergence of N-heterocyclic carbenes as ligands across the Periodic Table had an
impact on various aspects of the coordination, organometallic, and catalytic chemistry of the …

Hydride complexes of copper, silver, and gold encompass a broad array of structures, and
their distinctive reactivity has enabled dramatic recent advances in synthesis and catalysis …

Bimetallic catalysis represents an alternative paradigm for coupling chemistry that
complements the more traditional single-site catalysis approach. In this perspective, recent …

We report here on a new series of CO2-reducing molecular catalysts based on Earth-
abundant elements that are very selective for the production of formic acid in …

Herein we present the catalytic activation of N2O at a BiI⇄ BiIII redox platform. The activation
of such a kinetically inert molecule was achieved by the use of bismuthinidene catalysts …

The field of carbon dioxide reduction by homogeneous early transition complexes (groups 3–
7) is reviewed. Many reactions with CO 2 have been studied with late transition metal …

Metal-free catalysts, such as graphene/carbon nanostructures, are highly cost-effective to
replace expensive noble metals for CO2 reduction if fundamental issues, such as active …