Bonds over electrons: proton coupled electron transfer at solid–solution interfaces

JM Mayer - Journal of the American Chemical Society, 2023 - ACS Publications
This Perspective argues that most redox reactions of materials at an interface with a protic
solution involve net proton-coupled electron transfer (PCET)(or other cation-coupled ET) …

Mechanism and kinetics of the hydrogen evolution reaction

A Lasia - international journal of hydrogen energy, 2019 - Elsevier
Hydrogen evolution reaction, HER, is the simplest electrocatalytic reaction. With
development of renewable energy sources electrolytic production of hydrogen becomes an …

Electrochemical reduction of gaseous nitrogen oxides on transition metals at ambient conditions

BH Ko, B Hasa, H Shin, Y Zhao… - Journal of the American …, 2022 - ACS Publications
Mitigating nitrogen oxide (NO x) emissions is critical to tackle global warming and improve
air quality. Conventional NO x abatement technologies for emission control suffer from a low …

Full atomistic reaction mechanism with kinetics for CO reduction on Cu (100) from ab initio molecular dynamics free-energy calculations at 298 K

T Cheng, H Xiao… - Proceedings of the …, 2017 - National Acad Sciences
A critical step toward the rational design of new catalysts that achieve selective and efficient
reduction of CO2 to specific hydrocarbons and oxygenates is to determine the detailed …

Promoting ethylene production over a wide potential window on Cu crystallites induced and stabilized via current shock and charge delocalization

H Sun, L Chen, L Xiong, K Feng, Y Chen… - Nature …, 2021 - nature.com
Abstract Electrochemical CO2 reduction (CO2RR) in a product-orientated and energy-
efficient manner relies on rational catalyst design guided by mechanistic understandings. In …

Electrochemical methods of real surface area determination of noble metal electrodes–an overview

M Łukaszewski, M Soszko, A Czerwiński - International Journal of …, 2016 - Elsevier
The electrochemical methods of real surface area determination of noble metal electrodes
and their alloys are summarized. These methods utilize hydrogen adsorption, surface oxide …

Standard and reversible hydrogen electrodes: Theory, design, operation, and applications

G Jerkiewicz - ACS Catalysis, 2020 - ACS Publications
Research in electrocatalysis as well as in physical and analytical electrochemistry typically
employs a three-electrode configuration comprising a working electrode (WE), a counter …

Elucidating effects of catalyst loadings and porous transport layer morphologies on operation of proton exchange membrane water electrolyzers

D Kulkarni, A Huynh, P Satjaritanun, M O'Brien… - Applied Catalysis B …, 2022 - Elsevier
Producing green hydrogen efficiently via proton exchange membrane water electrolysis
(PEMWE) is the key for achieving decarbonization targets. Iridium catalyst is expensive, and …

A critical review on hydrogen evolution electrocatalysis: Re‐exploring the volcano‐relationship

AR Zeradjanin, JP Grote, G Polymeros… - …, 2016 - Wiley Online Library
The “volcano”‐relationship for the electrocatalytic hydrogen evolution reaction seems to be a
generally accepted phenomenology in electrochemistry. Based on the Sabatier principle …

Comparison of electrochemical active surface area methods for various nickel nanostructures

E Cossar, MSE Houache, Z Zhang… - Journal of …, 2020 - Elsevier
Electrochemical processes, such as energy conversion and storage, water electrolysis and
other electrocatalytic processes call for expensive noble metal catalysts to provide efficient …