This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …

The precise construction of chiral molecules is a core research area in chemical science and
technology. Among the plethora of reported synthetic methods, asymmetric catalysis has …

Mechanism-guided reaction development is a well-appreciated research paradigm in
chemistry since the merging of mechanistic knowledge would accelerate the discovery of …

As an important class of platform molecules, planar chiral ferrocene carbonyl compounds
could be transformed into various functional groups offering facile synthesis of chiral ligands …

Planar chiral ferrocenyl phosphines have been employed as highly valuable ligands in
metal-catalyzed asymmetric reactions. However, their preparation remains a formidable …

The field of nickel catalysis has witnessed remarkable growth in recent years. However, the
use of nickel catalysts in enantioselective C–H activation remains a daunting challenge …

Chiral carbon–carbon (C–C) and carbon–heteroatom (C–X) bonds are pervasive and very
essential in natural products, bioactive molecules, and functional materials, and their …

Copper-catalyzed enantioselective C–H activation proceeding through an inner-sphere
mechanism remains a huge challenge. Herein, a copper-catalyzed enantioselective C–H …

One-step asymmetric synthesis of metallocenes with planar and central chirality was
developed by rhodium-catalyzed desymmetric cyclization. The reactions of prochiral 1, 2 …

Kinetic resolution is a powerful strategy for the isolation of enantioenriched compounds from
racemic mixtures, and the development of selective catalytic processes is an active area of …