Kinetics of chemical processes: From molecular to industrial scale

GB Marin, VV Galvita, GS Yablonsky - Journal of Catalysis, 2021 - Elsevier
Combining spectroscopic and transient kinetic techniques provides access to the
identification and quantification of active sites and corresponding turnover frequencies of …

Temporal analysis of products (TAP)—recent advances in technology for kinetic analysis of multi-component catalysts

JT Gleaves, G Yablonsky, X Zheng, R Fushimi… - Journal of Molecular …, 2010 - Elsevier
This paper presents an overview of the evolution, advancements, and capabilities of the
temporal analysis of products (TAP) reactor system as a unique catalyst characterization …

Extracting knowledge from data through catalysis informatics

AJ Medford, MR Kunz, SM Ewing, T Borders… - Acs …, 2018 - ACS Publications
Catalysis informatics is a distinct subfield that lies at the intersection of cheminformatics and
materials informatics but with distinctive challenges arising from the dynamic, surface …

Forty years of temporal analysis of products

K Morgan, N Maguire, R Fushimi, JT Gleaves… - Catalysis Science & …, 2017 - pubs.rsc.org
A detailed understanding of reaction mechanisms and kinetics is required in order to
develop and optimize catalysts and catalytic processes. While steady-state investigations …

Dynamic methods for catalytic kinetics

RJ Berger, F Kapteijn, JA Moulijn, GB Marin… - Applied Catalysis A …, 2008 - Elsevier
The application of various transient techniques in heterogeneous catalysis (TAP, step-
response experiments, SSITKA, TEOM), with the aim to determine reaction kinetics for …

[HTML][HTML] A temporal analysis of products (TAP) study of C2-C4 alkene reactions with a well-defined pool of methylating species on ZSM-22 zeolite

EA Redekop, A Lazzarini, S Bordiga, U Olsbye - Journal of catalysis, 2020 - Elsevier
Reactions between alkenes and methanol or dimethyl ether (DME) on zeolite catalysts are
involved in industrial processes that are highly relevant for the transition to renewable …

Site-specific scaling relations observed during methanol-to-olefin conversion over ZSM-5 catalysts

T Omojola - Chemical Engineering Science, 2022 - Elsevier
The conversion of methanol over ZSM-5 catalysts was studied using step response and
temperature-programmed desorption and surface reaction analyses in a temporal analysis …

Data driven reaction mechanism estimation via transient kinetics and machine learning

MR Kunz, A Yonge, Z Fang, R Batchu… - Chemical Engineering …, 2021 - Elsevier
Understanding the set of elementary steps and kinetics in each reaction is extremely
valuable to make informed decisions about creating the next generation of catalytic …

Decoding complexity of chemical reactions

GS Yablonsky - Theoretical Foundations of Chemical Engineering, 2014 - Springer
Decoding Complexity of Chemical Reactions1 Page 1 ISSN 0040 5795, Theoretical
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …

Transient kinetic experiments within the high conversion domain: the case of ammonia decomposition

Y Wang, MR Kunz, S Siebers, H Rollins, J Gleaves… - Catalysts, 2019 - mdpi.com
In the development of catalytic materials, a set of standard conditions is needed where the
kinetic performance of many samples can be compared. This can be challenging when a …