Kinetics of chemical processes: From molecular to industrial scale
Combining spectroscopic and transient kinetic techniques provides access to the
identification and quantification of active sites and corresponding turnover frequencies of …
identification and quantification of active sites and corresponding turnover frequencies of …
Temporal analysis of products (TAP)—recent advances in technology for kinetic analysis of multi-component catalysts
JT Gleaves, G Yablonsky, X Zheng, R Fushimi… - Journal of Molecular …, 2010 - Elsevier
This paper presents an overview of the evolution, advancements, and capabilities of the
temporal analysis of products (TAP) reactor system as a unique catalyst characterization …
temporal analysis of products (TAP) reactor system as a unique catalyst characterization …
Extracting knowledge from data through catalysis informatics
AJ Medford, MR Kunz, SM Ewing, T Borders… - Acs …, 2018 - ACS Publications
Catalysis informatics is a distinct subfield that lies at the intersection of cheminformatics and
materials informatics but with distinctive challenges arising from the dynamic, surface …
materials informatics but with distinctive challenges arising from the dynamic, surface …
Forty years of temporal analysis of products
K Morgan, N Maguire, R Fushimi, JT Gleaves… - Catalysis Science & …, 2017 - pubs.rsc.org
A detailed understanding of reaction mechanisms and kinetics is required in order to
develop and optimize catalysts and catalytic processes. While steady-state investigations …
develop and optimize catalysts and catalytic processes. While steady-state investigations …
Dynamic methods for catalytic kinetics
The application of various transient techniques in heterogeneous catalysis (TAP, step-
response experiments, SSITKA, TEOM), with the aim to determine reaction kinetics for …
response experiments, SSITKA, TEOM), with the aim to determine reaction kinetics for …
[HTML][HTML] A temporal analysis of products (TAP) study of C2-C4 alkene reactions with a well-defined pool of methylating species on ZSM-22 zeolite
Reactions between alkenes and methanol or dimethyl ether (DME) on zeolite catalysts are
involved in industrial processes that are highly relevant for the transition to renewable …
involved in industrial processes that are highly relevant for the transition to renewable …
Site-specific scaling relations observed during methanol-to-olefin conversion over ZSM-5 catalysts
T Omojola - Chemical Engineering Science, 2022 - Elsevier
The conversion of methanol over ZSM-5 catalysts was studied using step response and
temperature-programmed desorption and surface reaction analyses in a temporal analysis …
temperature-programmed desorption and surface reaction analyses in a temporal analysis …
Data driven reaction mechanism estimation via transient kinetics and machine learning
Understanding the set of elementary steps and kinetics in each reaction is extremely
valuable to make informed decisions about creating the next generation of catalytic …
valuable to make informed decisions about creating the next generation of catalytic …
Decoding complexity of chemical reactions
GS Yablonsky - Theoretical Foundations of Chemical Engineering, 2014 - Springer
Decoding Complexity of Chemical Reactions1 Page 1 ISSN 0040 5795, Theoretical
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …
Transient kinetic experiments within the high conversion domain: the case of ammonia decomposition
In the development of catalytic materials, a set of standard conditions is needed where the
kinetic performance of many samples can be compared. This can be challenging when a …
kinetic performance of many samples can be compared. This can be challenging when a …