Homogeneous catalysis for sustainable energy: hydrogen and methanol economies, fuels from biomass, and related topics

A Kumar, P Daw, D Milstein - Chemical reviews, 2021 - ACS Publications
As the world pledges to significantly cut carbon emissions, the demand for sustainable and
clean energy has now become more important than ever. This includes both production and …

Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions

K Das, S Waiba, A Jana, B Maji - Chemical Society Reviews, 2022 - pubs.rsc.org
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Reversible hydrogenation of carbon dioxide to formic acid using a Mn-pincer complex in the presence of lysine

D Wei, R Sang, P Sponholz, H Junge, M Beller - Nature Energy, 2022 - nature.com
Efficient hydrogen storage and release are essential for effective use of hydrogen as an
energy carrier. In principle, formic acid could be used as a convenient hydrogen storage …

First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Chiral tridentate ligands in transition metal-catalyzed asymmetric hydrogenation

H Wang, J Wen, X Zhang - Chemical Reviews, 2021 - ACS Publications
Asymmetric hydrogenation (AH) of double bonds has been one of the most effective
methods for the preparation of chiral molecules and for the synthesis of important chiral …

Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions

Y Wang, M Wang, Y Li, Q Liu - Chem, 2021 - cell.com
The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …

Fatty acids and their derivatives as renewable platform molecules for the chemical industry

U Biermann, UT Bornscheuer… - Angewandte Chemie …, 2021 - Wiley Online Library
Oils and fats of vegetable and animal origin remain an important renewable feedstock for the
chemical industry. Their industrial use has increased during the last 10 years from 31 to 51 …

Influence of solvent structure and hydrogen bonding on catalysis at solid–liquid interfaces

DS Potts, DT Bregante, JS Adams, C Torres… - Chemical Society …, 2021 - pubs.rsc.org
Solvent molecules interact with reactive species and alter the rates and selectivities of
catalytic reactions by orders of magnitude. Specifically, solvent molecules can modify the …

A Tailored Versatile and Efficient NHC‐Based NNC‐Pincer Manganese Catalyst for Hydrogenation of Polar Unsaturated Compounds

Z Wei, H Li, Y Wang, Q Liu - Angewandte Chemie, 2023 - Wiley Online Library
The reactivity of metal‐hydride complexes can be harnessed by the modification of ancillary
ligands. With the aim of improving the hydride‐donor ability of the key Mn− H intermediate …