Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …
Interface structure and dynamics in polymer‐nanoparticle hybrids: a review on molecular mechanisms underlying the improved interfaces
MA Sattar - ChemistrySelect, 2021 - Wiley Online Library
In a nano‐assembly of soft polymer chains and hard filler nanoparticles (NPs), the
intermolecular interactions at the polymer‐filler interface lead to variations in viscoelastic …
intermolecular interactions at the polymer‐filler interface lead to variations in viscoelastic …
Big effect of small nanoparticles: a shift in paradigm for polymer nanocomposites
Polymer nanocomposites (PNCs) are important materials that are widely used in many
current technologies and potentially have broader applications in the future due to their …
current technologies and potentially have broader applications in the future due to their …
Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites
It is generally believed that the strength of the polymer–nanoparticle interaction controls the
modification of near-interface segmental mobility in polymer nanocomposites (PNCs) …
modification of near-interface segmental mobility in polymer nanocomposites (PNCs) …
Progress towards a phenomenological picture and theoretical understanding of glassy dynamics and vitrification near interfaces and under nanoconfinement
KS Schweizer, DS Simmons - The Journal of chemical physics, 2019 - pubs.aip.org
The nature of alterations to dynamics and vitrification in the nanoscale vicinity of interfaces—
commonly referred to as “nanoconfinement” effects on the glass transition—has been an …
commonly referred to as “nanoconfinement” effects on the glass transition—has been an …
Unexpected molecular weight effect in polymer nanocomposites
The properties of the interfacial layer between the polymer matrix and nanoparticles largely
determine the macroscopic properties of polymer nanocomposites (PNCs). Although the …
determine the macroscopic properties of polymer nanocomposites (PNCs). Although the …
Interfacial properties of polymer nanocomposites: Role of chain rigidity and dynamic heterogeneity length scale
While it is known that the properties of polymer nanocomposites are largely dominated by
the interfacial layer around nanoparticles, the molecular parameters controlling the …
the interfacial layer around nanoparticles, the molecular parameters controlling the …
[HTML][HTML] Focus: Structure and dynamics of the interfacial layer in polymer nanocomposites with attractive interactions
In recent years it has become clear that the interfacial layer formed around nanoparticles in
polymer nanocomposites (PNCs) is critical for controlling their macroscopic properties. The …
polymer nanocomposites (PNCs) is critical for controlling their macroscopic properties. The …
Analyzing the interfacial layer properties in polymer nanocomposites by broadband dielectric spectroscopy
Probing the properties of the interfacial layer between the polymer matrix and nanoparticles
in polymer nanocomposites (PNCs) remains a challenging task. Here, we apply three …
in polymer nanocomposites (PNCs) remains a challenging task. Here, we apply three …
Influence of the bound polymer layer on nanoparticle diffusion in polymer melts
PJ Griffin, V Bocharova, LR Middleton… - ACS Macro …, 2016 - ACS Publications
We measure the center-of-mass diffusion of silica nanoparticles (NPs) in entangled poly (2-
vinylpyridine)(P2VP) melts using Rutherford backscattering spectrometry. While these NPs …
vinylpyridine)(P2VP) melts using Rutherford backscattering spectrometry. While these NPs …