Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

The chemistry of the early to middle actinide elements (Th− Cm) is of critical importance to
the nuclear energy industry. A need for knowledge of the chemical behavior and speciation …

This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …

Molecular complexes of uranium are capable of activating a range of industrially and
economically important small molecules such as CO, CO2, and N2; new and often …

The structure of and bonding in two base-free terminal actinide imido metallocenes,[η5-1, 2,
4-(Me3C) 3C5H2] 2An═ N (p-tolyl)(An= U (1), Th (1′)) are compared and connected to …

Although examples of multiple bonds between actinide elements and main‐group elements
are quite common, studies of the multiple bonds between actinide elements and transition …

Syntheses of rare examples of U (V) methyl and U (IV) ylide complexes are reported.
Reaction of the previously reported U (IV) imido complex [(C5Me5) 2U (py)(═ NMes)](py …

Reactivity studies on the sterically crowded [(C5Me5) 2U] 2 (μ− η6: η6-C6H6), 1, have
revealed that η1-ligands can displace one of the normally inert (η5-C5Me5) 1− ligands in …

Addition of p-tolylNH2 to a toluene solution of [η5-1, 3-(Me3C) 2C5H3] 2UMe2 (1) in the
presence of 4-dimethylaminopyridine (dmap) yields the Lewis base-supported terminal …